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author:

Zhou, Zeyang (Zhou, Zeyang.) [1] | Chang, Qingda (Chang, Qingda.) [2] | Chen, Rui (Chen, Rui.) [3] | Jin, Pengfei (Jin, Pengfei.) [4] | Yin, Baipeng (Yin, Baipeng.) [5] | Zhang, Chuang (Zhang, Chuang.) [6] | Yao, Jiannian (Yao, Jiannian.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

Light-emitting electrochemical cells (LECs) are appealing for cost-effective, large-area emission applications; however, their luminescence efficiency is significantly limited by exciton annihilation caused by high concentration polarons. Here, we present thermally activated delayed fluorescence (TADF) sensitized fluorescence LECs (TSF-LECs) that achieve a record 9% EQE. The TADF sensitizers with rapid reverse intersystem crossing (RISC) rates can effectively convert triplet excitons to singlet excitons in LECs, thereby establishing a more efficient overall energy transfer pathway. Importantly, magneto-electroluminescence measurements indicate that the additional RISC route in TSF-LECs significantly suppresses the annihilation of triplet excitons and thus reduces exciton loss under high concentration polaron conditions. Compared to LECs without a sensitizer, TSF-LECs exhibit improved EQE and luminance, extended operational lifetimes, and suppressed efficiency roll-off. A flexible display prototype based on TSF-LECs was further fabricated, capable of stably displaying high-brightness preset patterns for extended periods. The exploration of the exciton dynamics in high concentration polaron environments offers valuable insights for future developments in high-efficiency LEC technology.

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Community:

  • [ 1 ] [Zhou, Zeyang]Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China
  • [ 2 ] [Chang, Qingda]Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China
  • [ 3 ] [Chen, Rui]Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China
  • [ 4 ] [Jin, Pengfei]Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China
  • [ 5 ] [Yin, Baipeng]Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China
  • [ 6 ] [Zhang, Chuang]Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China
  • [ 7 ] [Yao, Jiannian]Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China
  • [ 8 ] [Zhou, Zeyang]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 9 ] [Chang, Qingda]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 10 ] [Chen, Rui]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 11 ] [Jin, Pengfei]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 12 ] [Yao, Jiannian]Fuzhou Univ, Inst Mol Engn Plus, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Yin, Baipeng]Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China;;[Zhang, Chuang]Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China;;

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Source :

PHYSICAL CHEMISTRY CHEMICAL PHYSICS

ISSN: 1463-9076

Year: 2024

Issue: 37

Volume: 26

Page: 24498-24505

2 . 9 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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