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author:

Zhang, Jun (Zhang, Jun.) [1] | Zeng, Libin (Zeng, Libin.) [2] | Yang, Can (Yang, Can.) [3] (Scholars:阳灿)

Indexed by:

Scopus SCIE

Abstract:

Effective advancements for H 2 S removal are desperately expected to meet security and ecological necessities as natural guidelines on H 2 S emissions. Selective catalytic oxidation, as a green technology, has attracted attention owing to its direct conversion of H 2 S to S without thermodynamic constraints. Herein, we report a carbonencapsulated WO 3 (C@WO 3 -300) catalyst with nearly 100 % H 2 S conversion and 99 % S selectivity. Importantly, it likewise accomplishes noteworthy catalytic stability (over 120 h of continuous operation) and water resistance. Excellent durability may be attributed to the ideal porosity of C@WO 3 , which facilitates the adsorption and activation of H 2 S and O 2 . Additionally, the abundant lone pair electrons of carbon support can optimize the chemical environment of WO 3 -based catalysts and thereby benefit the O 2 activation. This study provides a new avenue for the rational design of efficient and durable catalysts for continuous catalytic oxidative desulfurization.

Keyword:

Desulfurization Porous Carbon-EncapsulatedWO3 Selective catalytic oxidation Water resistance

Community:

  • [ 1 ] [Zhang, Jun]Fujian Police Coll, Fuzhou 350007, Peoples R China
  • [ 2 ] [Zeng, Libin]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
  • [ 3 ] [Yang, Can]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • [Yang, Can]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China;;

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Source :

SURFACES AND INTERFACES

ISSN: 2468-0230

Year: 2024

Volume: 51

5 . 7 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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