Two　o-carborane-hybridized　macrocyclic　arenes　have　been　synthesized　via　Friedel-Crafts　alkylation　of　carborane　diaryl　derivatives.　The　single-crystal　X-ray　diffraction　analysis　clearly　revealed　their　cavity　structure　and　intermolecular　interaction　force.　These　novel　macrocycles　exhibited　aggregation-induced　luminescence　and　intramolecular　charge　transfer　properties　and　also　significant　selectivity　towards　nitro　explosive　compounds.　This　work　provided　a　method　for　the　synthesis　of　hybridized　macrocyclic　arenes.