Enhanced　ordered　intermetallic　compounds　excel　in　catalyzing　the　oxygen　reduction　reaction　(ORR).　We　introduce　a　novel　synthesis　strategy　based　on　molecularly　engineered　to　address　challenges　in　high-temperature　annealing.　It　involves　the　synthesis　of　carbon　platforms　with　rich　edge　sites,　which　serve　as　effective　anchoring　points　for　nanoparticles.　By　utilizing　sulfur　anchoring,　we　synthesize　ordered　Pt-Co　intermetallic　with　Pt-rich　shells　(o-PtCo@Pt)　that　exhibit　remarkable　ORR　performance.　Ordered　arrangement　of　Pt-Co　endows　Pt-shell　with　compression　stress　and　enhances　the　oxidation　resistance　of　Pt/Co　sites.　O-PtCo@Pt　exhibits　high　mass　activity　(MA,　0.53　A　mgPt-　1)　and　specific　activity　(SA,　1.17　mA　cm-2).　It　exhibits　remarkable　as　cathodic　catalyst　in　proton　exchange　membrane　fuel　cells.　It　achieves　power　density　of　1.14　W　cm-2　at　2.0　A　cm-2,　with　MA　of　0.50　A　mgPt-　1　at　0.9　V.　It　maintains　stability　with　only　8　%　power　density　loss　after　30,000　cycles,　retaining　MA　of　0.35　A　mgPt-　1.