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author:

Wu, J. (Wu, J..) [1] | Wang, R. (Wang, R..) [2] | Zhang, R. (Zhang, R..) [3] | Portale, G. (Portale, G..) [4] | Solano, E. (Solano, E..) [5] | Liu, X. (Liu, X..) [6] | Gao, F. (Gao, F..) [7]

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Scopus

Abstract:

We report a simple, effective, and universal lattice reconstruction approach to improve the quality of perovskite films by using nonpolar solvents with high Gutmann donor numbers (DNs). We find that high-DN nonpolar solvents, for instance, ethyl acetate, can interact with perovskite precursors. Such a solvent can make the perovskite lattice more ordered and “harder” and promote the formation of heterostructures with low-dimensional perovskite impurities and residual solvent molecules. As a result, the lattice-reconstructed perovskite films exhibit reduced defect densities and suppressed ion migration. The resultant mixed-halide blue perovskite light-emitting diodes (PeLEDs) show greatly enhanced tolerance to high driving current densities and voltages, demonstrating high brightness, outstanding color stability and low efficiency roll-off. Our work provides a deep understanding of the interactions between nonpolar solvents and perovskites and offers useful guidelines for further development of high-power PeLEDs. (Figure presented.) © The Author(s) 2024.

Keyword:

color stability high brightness ion migration low efficiency roll-off mixed halide perovskite

Community:

  • [ 1 ] [Wu J.]Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, 581 83, Sweden
  • [ 2 ] [Wu J.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Wang R.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Zhang R.]Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, 581 83, Sweden
  • [ 5 ] [Portale G.]Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, Groningen, 9747AG, Netherlands
  • [ 6 ] [Solano E.]Experiments Division ALBA synchrotron Carrer de la Llum 2-2608290 - Cerdanyola del Vallès, Barcelona, Spain
  • [ 7 ] [Liu X.]Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, 581 83, Sweden
  • [ 8 ] [Gao F.]Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, 581 83, Sweden

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Source :

Science China Materials

ISSN: 2095-8226

Year: 2024

Issue: 11

Volume: 67

Page: 3553-3560

6 . 8 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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