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author:

Chen, M. (Chen, M..) [1] | Liu, F.-M. (Liu, F.-M..) [2] | Zhao, M.-Y. (Zhao, M.-Y..) [3] | Qian, X. (Qian, X..) [4] (Scholars:钱兴) | Yuan, Z.-Y. (Yuan, Z.-Y..) [5] | Wan, R. (Wan, R..) [6] | Li, C.-S. (Li, C.-S..) [7] | Zhang, X. (Zhang, X..) [8] | Wang, S. (Wang, S..) [9]

Indexed by:

EI Scopus SCIE

Abstract:

Fe3N nanocrystals embedded in cracked N-doped carbon nanotubes (Fe3N@NCNT) with a cowpea-like shape are innovatively prepared by metal-catalyzed graphitization and nitridization processes based on melamine and FeC2O4 precursor. The new in-situ synthesis strategy is proved to be effective to open the NCNT using a migratory metal carbide nanocatalyst via expansion effect and fabricate a metal nitride embedded NCNT with fully active ingredients. The detailed tip-growth mechanism of cracked NCNT with latitudinal-longitudinal graphene layers is studied by in-situ XRD analysis of the phase evolution of melamine and FeC2O4, and ex-situ SEM/TEM investigation of the topography correlation of NCNT and Fe3C floating catalyst. The Fe3N@NCNT microclews based anodes have a moderate carbon content of 35.45 wt%, electroactive NCNT conductive network, abundant microcracks and an open short-cavity system, showing a stable discharge capacity of 667 mAh g−1 at 0.1C, outstanding rate capability of 448 mAh g−1 at 5C and remarkable long-term cycling stability of 546 mAh g−1 after 600 cycles at 1C. The combined good electronic/ionic conductivity of cracked NCNT and robust mechanical stability of geometrically confined Fe3N nanoparticles contribute to the excellent redox activities, stabilized solid-electrolyte-interphase film and cycling durability of Fe3N@NCNT. © 2024 Elsevier Ltd

Keyword:

Anodes Carbon nanotubes Growth mechanism Iron nitrides Lithium-ion batteries

Community:

  • [ 1 ] [Chen M.]College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, 464000, China
  • [ 2 ] [Liu F.-M.]College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, 464000, China
  • [ 3 ] [Zhao M.-Y.]College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, 464000, China
  • [ 4 ] [Qian X.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Yuan Z.-Y.]School of Materials Science and Engineering, Nankai University, Tianjin, 300071, China
  • [ 6 ] [Wan R.]College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, 464000, China
  • [ 7 ] [Li C.-S.]School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou, 215009, China
  • [ 8 ] [Zhang X.]College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, 464000, China
  • [ 9 ] [Wang S.]College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, 464000, China

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Source :

Carbon

ISSN: 0008-6223

Year: 2024

Volume: 230

1 0 . 5 0 0

JCR@2023

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ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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