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[期刊论文]

The curing kinetics and properties of self-healing and thermally conductive polymeric composites based on ethylene vinyl acetate copolymer filled with nano alumina

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author:

Lin, Hongyi (Lin, Hongyi.) [1] | Zhang, Yuchi (Zhang, Yuchi.) [2] | Gao, Renjin (Gao, Renjin.) [3] | Unfold

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EI

Abstract:

We have investigated a self-healing thermally conductive Ethylene-vinyl acetate (EVA) hot melt adhesive (NAEDS, which denotes the addition of nano-alumina and disulfide bonded EVA hot melt adhesives) that can be used to effectively solve adhesive layer separation problem in photovoltaic (PV) modules and the difficulty of recycling. More specifically, we used diallyl disulfide as a cross-linking agent for EVA and alumina nanofillers as a reinforcing phase. The nano alumina filler gave the EVA better thermal conductivity. We used FTIR, SEM, and DSC to characterize and analyze NAEDS properties. The disulfide bonds in NAEDS underwent a rearrangement reaction under ultraviolet light, resulting in the self-healing of the resin (self-healing efficiency of 78.8%). The added nano alumina not only reduced the resin curing activation energy, improving its curing performance but also enhanced its thermal conductivity, achieving a 2.61 W/(m*k) thermal conductivity coefficient. The overall NAEDS performance is improved. © The Author(s) 2024.

Keyword:

Activation energy Adhesives Alumina Aluminum oxide Capillary flow Crosslinking Curing Ethylene Polyvinyl acetates Resins Self-healing materials Sulfur compounds Thermal conductivity Thermoplastic elastomers

Community:

  • [ 1 ] [Lin, Hongyi]Fujian Engineering and Research Center of New Chinese lacquer Materials, Minjiang University, Fuzhou, China
  • [ 2 ] [Lin, Hongyi]College of Chemical Engineering, Fuzhou University, Fuzhou, China
  • [ 3 ] [Zhang, Yuchi]Fujian Engineering and Research Center of New Chinese lacquer Materials, Minjiang University, Fuzhou, China
  • [ 4 ] [Zhang, Yuchi]Fujian Provincial University Engineering Research Center of Green Materials and Chemical Engineering, Minjiang University, Fuzhou, China
  • [ 5 ] [Gao, Renjin]Fujian Engineering and Research Center of New Chinese lacquer Materials, Minjiang University, Fuzhou, China
  • [ 6 ] [Gao, Renjin]Fujian Key Laboratory of Functional Marine Sensing Materials, Minjiang University, Fuzhou, China
  • [ 7 ] [Wang, Liwei]Fujian Engineering and Research Center of New Chinese lacquer Materials, Minjiang University, Fuzhou, China
  • [ 8 ] [Wang, Liwei]Fujian Provincial University Engineering Research Center of Green Materials and Chemical Engineering, Minjiang University, Fuzhou, China
  • [ 9 ] [Xia, Jianrong]Fujian Engineering and Research Center of New Chinese lacquer Materials, Minjiang University, Fuzhou, China
  • [ 10 ] [Xia, Jianrong]College of Chemical Engineering, Fuzhou University, Fuzhou, China
  • [ 11 ] [Xia, Jianrong]Fujian Provincial University Engineering Research Center of Green Materials and Chemical Engineering, Minjiang University, Fuzhou, China
  • [ 12 ] [Xue, Hanyu]Fujian Engineering and Research Center of New Chinese lacquer Materials, Minjiang University, Fuzhou, China
  • [ 13 ] [Xue, Hanyu]College of Chemical Engineering, Fuzhou University, Fuzhou, China
  • [ 14 ] [Xue, Hanyu]Fujian Provincial University Engineering Research Center of Green Materials and Chemical Engineering, Minjiang University, Fuzhou, China

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Source :

Journal of Plastic Film and Sheeting

ISSN: 8756-0879

Year: 2024

Issue: 3

Volume: 40

Page: 283-306

2 . 1 0 0

JCR@2023

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

30 Days PV: 2

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