Ferrocene-based conjugated macrocycles: shotgun synthesis, size-dependent properties and tunable fluorescence intensity - Details

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Abstract：

The　synthesis,　structure,　and　size-dependent　properties　of　ferrocene-embedded　conjugated　macrocycles　are　described.　The　one-pot,　two-component　“shotgun”　synthesis　greatly　expands　the　structural　diversity　and　functionality　of　nanohoops.　These　η5-type　coordination　metal-nanohoops　exhibit　intriguing　properties,　including　reversible　redox　behavior　and　collisional　quenching　with　fullerenes.　Notably,　the　addition　of　oxidants　enhances　their　fluorescence　intensity,　while　fullerenes　quench　it.　Detailed　theoretical　and　experimental　studies　reveal　that　fine-tuning　the　nanohoop　size　significantly　influences　not　only　the　molecular　conformation　but　also　its　electronic　structure　and　photophysical　properties.　©　2024　The　Royal　Society　of　Chemistry.

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[ 1 ] [Zhu L.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Xu J.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Lan B.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Chen X.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Kono H.]Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Chikusa, Nagoya, 464-8602, Japan
[ 6 ] [Xu H.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Fuzhou University, Fuzhou, 350108, China
[ 7 ] [Yan J.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Fuzhou University, Fuzhou, 350108, China
[ 8 ] [Li W.]Henan Key Laboratory of Biomolecular Recognition and Sensing, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu, 476000, China
[ 9 ] [Yagi A.]Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Chikusa, Nagoya, 464-8602, Japan
[ 10 ] [Yuan Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Fuzhou University, Fuzhou, 350108, China
[ 11 ] [Itami K.]Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Chikusa, Nagoya, 464-8602, Japan
[ 12 ] [Li Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Fuzhou University, Fuzhou, 350108, China

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Organic Chemistry Frontiers

ISSN： 2052-4110

Year： 2024

Issue： 18

Volume： 11

Page： 5130-5137

4 . 6 0 0

JCR@2023

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30 Days PV： 2

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