Two Mn(II)-Bridged Silverton-Type [UMo12O42]8- Polyoxometalates with Catalytic Activity for the Synthesis of Pyrazoles - Details

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Two　Mn(II)-bridged　Silverton-type　{UMo12O42}-based　polyoxomolybdates　with　different　three-dimensional　structures,　Na6(H2O)12[Mn(UMo12O42)]　(NaMn)　and　(NH4)2[K2Na6(μ4-O)2(H2O)1.2Mn(UMo12O42)]·4.6H2O　(KMn),　were　hydrothermally　synthesized　and　further　characterized,　demonstrating　a　feasible　strategy　for　the　assembly　of　Silverton-type　polyoxomolybdates.　Additionally,　NaMn　is　demonstrated　to　be　a　good　heterogeneous　catalyst　in　the　condensation　cyclization　reaction　of　hydrazines　and　1,3-diketones,　and　a　range　of　valuable　pyrazoles　were　produced　in　up　to　99%　yield.　(Figure　Presented).　©　2024　American　Chemical　Society.

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Catalyst activity Condensation reactions Cyclization Manganese compounds

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[ 1 ] [Lin, Xiao-Ling]School of Chemistry and Material Science, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang; 330013, China
[ 2 ] [Hu, Qi-Long]School of Chemistry and Material Science, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang; 330013, China
[ 3 ] [Tan, Ke-Xin]School of Chemistry and Material Science, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang; 330013, China
[ 4 ] [Chen, Xue-Jiao]School of Chemistry and Material Science, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang; 330013, China
[ 5 ] [Yang, Guo-Ping]School of Chemistry and Material Science, Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China University of Technology, Nanchang; 330013, China
[ 6 ] [Yang, Guo-Ping]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated Materials, College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 7 ] [Yang, Guo-Ping]Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing; 100084, China
[ 8 ] [Wei, Yong-Ge]Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing; 100084, China

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Inorganic Chemistry

ISSN： 0020-1669

Year： 2024

Issue： 27

Volume： 63

Page： 12469-12474

4 . 3 0 0

JCR@2023

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