Low-temperature　rechargeable　aqueous　zinc　metal　batteries　(AZMBs)　as　highly　promising　candidates　for　energy　storage　are　largely　hindered　by　huge　desolvation　energy　barriers　and　depressive　Zn2+　migration　kinetics.　In　this　work,　a　superfast　zincophilic　ion　conductor　of　layered　zinc　silicate　nanosheet　(LZS)　is　constructed　on　a　metallic　Zn　surface,　as　an　artificial　layer　and　ion　diffusion　accelerator.　The　experimental　and　simulation　results　reveal　the　zincophilic　ability　and　layer　structure　of　LZS　not　only　promote　the　desolvation　kinetics　of　[Zn(H2O)6]2+　but　also　accelerate　the　Zn2+　transport　kinetics　across　the　anode/electrolyte　interface,　guiding　uniform　Zn　deposition.　Benefiting　from　these　features,　the　LZS-modified　Zn　anodes　showcase　long-time　stability　(over　3300 h)　and　high　Coulombic　efficiency　with　≈99.8%　at　2 mA　cm−2,　respectively.　Even　reducing　the　environment　temperature　down　to　0 °C,　ultralong　cycling　stability　up　to　3600 h　and　a　distinguished　rate　performance　are　realized.　Consequently,　the　assembled　Zn@LZS//V2O5-x　full　cells　deliver　superior　cyclic　stability　(344.5　mAh　g−1　after　200　cycles　at　1　A　g−1)　and　rate　capability　(285.3　mAh　g−1　at　10　A　g−1)　together　with　a　low　self-discharge　rate,　highlighting　the　bright　future　of　low-temperature　AZMBs.　©　2024　The　Authors.　Advanced　Science　published　by　Wiley-VCH　GmbH.