Π-Bridge Modulations in D–π–A Conjugated Microporous Polymers to Facilitate Charge Separation and Transfer Kinetics for Efficient Photocatalysis - Details

author：

Indexed by：

Scopus

Abstract：

The　burgeoning　field　of　conjugated　microporous　polymers　(CMPs)　has　generated　widespread　interest　due　to　their　potential　as　photocatalysts　for　hydrogen　production　from　water.　Nevertheless,　their　photocatalytic　performance　is　sometimes　hindered　by　inadequate　charge　separation　and　transfer,　coupled　with　rapid　charge　recombination.　Herein,　a　strategy　to　enhance　photocatalytic　performance　via　the　customization　of　π-bridges　through　the　modulation　of　heteroatoms　in　a　series　of　donor-π-acceptor　(D-π-A)　CMPs　is　proposed.　This　affords　optimized　energy　levels　and　improved　charge　separation　and　transfer,　thus　boosting　photocatalytic　efficiency.　Among　various　heteroatom　substitutions,　S-doped　CMP　(10 mg)　demonstrates　the　highest　photocatalytic　hydrogen　evolution　rate　of　203 µmol h−1　(AQY450nm = 7.4%)　under　visible　light　irradiation.　Subsequent　experimental　analysis　reveals　its　superior　photocatalytic　performance　can　be　largely　related　to　its　minimized　exciton　binding　energy,　facilitated　charge　transfer　efficiency,　and　impeded　charge　recombination　among　these　heteroatom-doped　D-π-A　CMPs.　This　research　paves　the　way　for　the　rational　design　and　modification　of　organic　semiconductors　for　advanced　solar-driven　photocatalysis　by　promoting　charge　separation　and　transfer.　©　2024　Wiley-VCH　GmbH.

Keyword：

conjugated microporous polymers D-π-A hydrogen evolution photocatalysis

Community：

[ 1 ] [Li C.]State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry and Key Laboratory of Molecular Synthesis and Function Discovery, Fuzhou University, Fuzhou, 350116, China
[ 2 ] [Xu H.]State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry and Key Laboratory of Molecular Synthesis and Function Discovery, Fuzhou University, Fuzhou, 350116, China
[ 3 ] [Xiong H.]State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an, 710072, China
[ 4 ] [Xia S.]State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry and Key Laboratory of Molecular Synthesis and Function Discovery, Fuzhou University, Fuzhou, 350116, China
[ 5 ] [Peng X.]State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an, 710072, China
[ 6 ] [Xu F.]State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an, 710072, China
[ 7 ] [Chen X.]State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry and Key Laboratory of Molecular Synthesis and Function Discovery, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address：

Email：

Related Keywords：

Π-Bridge Modulations in D-π-A Conjugated Microporous Polymers to Facilitate Charge Separation and Transfer Kinetics for Efficient Photocatalysis
2024，ADVANCED FUNCTIONAL MATERIALS
Room Temperature Synthesis of Heptazine-Based Microporous Polymer Networks as Photocatalysts for Hydrogen Evolution
2013，MACROMOLECULAR RAPID COMMUNICATIONS
Tunable Synthesis of Conjugated Microporous Polymers and Their Adsorption Performance Toward Heavy Metals
2025，MACROMOLECULAR CHEMISTRY AND PHYSICS
Tunable Surface Area, Porosity, and Function in Conjugated Microporous Polymers
2019，ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Molecular Dipole-Induced Photoredox Catalysis for Hydrogen Evolution over Self-Assembled Naphthalimide Nanoribbons
2022，ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Type
Departments

All Years Choose Year From to