Side-Chain Type Ferrocene Macrocycles - Details

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Abstract：

A　class　of　side-chain　type　ferrocene　macrocycles　with　a　radially　conjugated　system　is　introduced　in　this　study.　The　stereo　configurations　of　these　ferrocene　rings　were　determined　through　single-crystal　X-ray　diffraction　analysis.　Notably,　in　the　solid　state,　the　ferrocene　rings　exhibit　a　distinctive　herringbone　stacking　pattern　imposed　by　a　ferrocene-to-ring　host-guest　interaction.　Through　UV-vis　absorption　spectroscopy,　electrochemical　measurements,　and　theoretical　calculations,　valuable　insights　into　the　electronic　properties　of　these　rings　were　obtained.　In　addition,　the　single　crystal　of　macrocycle　A2B　demonstrates　a　second-order　nonlinear　optical　response.　As　a　class　of　organometallic　nanorings,　this　work　holds　great　potential　for　further　exploration　in　the　fields　of　organometallic　chemistry,　molecular　electronics,　and　host-guest　chemistry.　©　2024　The　Authors.　Co-published　by　University　of　Science　and　Technology　of　China　and　American　Chemical　Society.

Keyword：

Conjugated Macrocycles Ferrocene Nanoring Organometallic Macrocycles Second-Order Nonlinear Optical

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[ 1 ] [Lan B.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Xu J.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Zhu L.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Chen X.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Kono H.]Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Nagoya, 464-8602, Japan
[ 6 ] [Wang P.]School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin, 300350, China
[ 7 ] [Zuo X.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 8 ] [Yan J.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 9 ] [Yagi A.]Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Nagoya, 464-8602, Japan
[ 10 ] [Zheng Y.]School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin, 300350, China
[ 11 ] [Chen S.]College of Chemistry and Material Science, Longyan University, Longyan, 364012, China
[ 12 ] [Yuan Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 13 ] [Itami K.]Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Nagoya, 464-8602, Japan
[ 14 ] [Li Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 15 ] [Li Y.]Key Laboratory of Advanced Carbon-Based Functional Materials (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China

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Side-Chain Type Ferrocene Macrocycles
2024，PRECISION CHEMISTRY

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Source ：

Precision Chemistry

ISSN： 2771-9316

Year： 2024

Issue： 4

Volume： 2

Page： 143-150

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SCOPUS Cited Count： 4

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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