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author:

Xu, Jincai (Xu, Jincai.) [1] | Zhao, Rui (Zhao, Rui.) [2] | Sun, Shihao (Sun, Shihao.) [3] | Wu, Zhengxiong (Wu, Zhengxiong.) [4] | Lu, Zhen (Lu, Zhen.) [5] | Xiao, Longqiang (Xiao, Longqiang.) [6] (Scholars:肖龙强) | Hou, Linxi (Hou, Linxi.) [7] (Scholars:侯琳熙)

Indexed by:

EI Scopus SCIE

Abstract:

Copper metal is essential to our production process, but it is highly corrosive in an ammonia environment and must be highly valued. Anti-corrosion coating is a simple and cost-effective method of preventing metal corrosion. In this study, a composite silane coating was prepared on copper using an impregnation method with mercaptopropyltriethoxysilane (TPTES) as the silane substrate and graphene oxide (GO) modified with isophorone diisocyanate (IPDI) or isocyanatopropyltriethoxysilane (IPTS) as filler to protect the copper from ammonia corrosion. The coating samples were hanging tested against ammonia corrosion by setting up two corrosive environments: ammonia gas and ammonia water. After 20 days of corrosion, the surfaces of the TPTES/ IPDI-GO and TPTES/IPTS-GO coatings remained unchanged under both ammonia environments and the corrosion rate was consistently low at 2-3 mu m/y. Additionally, the coating exhibited high protective qualities according to the electrochemical impedance spectroscopy (EIS) test in a 3.5% NaCl solution, which is attributed to the good dispersion that improves the densification and regularity of the coating. Meanwhile, IPTS-GO has a greater binding force with the coating matrix due to the increased number of reactive sites, resulting in further improved corrosion protection. This study provides an idea for research on ammonia-resistant coatings.

Keyword:

Ammonia corrosion Binding site Graphene oxide Silane coating

Community:

  • [ 1 ] [Xu, Jincai]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 2 ] [Wu, Zhengxiong]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 3 ] [Lu, Zhen]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 4 ] [Xiao, Longqiang]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 5 ] [Hou, Linxi]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 6 ] [Zhao, Rui]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 7 ] [Sun, Shihao]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 8 ] [Lu, Zhen]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 9 ] [Hou, Linxi]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 10 ] [Lu, Zhen]Fuzhou Univ, Fujian Key Lab Adv Mfg Technol Specialty Chem, Fuzhou 350116, Peoples R China
  • [ 11 ] [Xiao, Longqiang]Fuzhou Univ, Fujian Key Lab Adv Mfg Technol Specialty Chem, Fuzhou 350116, Peoples R China
  • [ 12 ] [Hou, Linxi]Fuzhou Univ, Fujian Key Lab Adv Mfg Technol Specialty Chem, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 侯琳熙

    [Hou, Linxi]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2024

Volume: 989

5 . 8 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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