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author:

Yu, X. (Yu, X..) [1] | Liu, J. (Liu, J..) [2] | Wu, H. (Wu, H..) [3] | Dong, Y. (Dong, Y..) [4] | Wu, X. (Wu, X..) [5] | Zheng, S. (Zheng, S..) [6] | Feng, S. (Feng, S..) [7] | Huang, W. (Huang, W..) [8]

Indexed by:

Scopus

Abstract:

Mechanochromic fluorophores and elastomers gain great potential in dynamic data encryption and anti-counterfeiting due to their instant responses, excellent handleability, high-throughput data-verification, and multi-dimensional security features. However, the reported mechanochromic fluorophores generally require solvent fuming or thermal annealing to revert their responses, sacrificing the handleability and lengthening the authentication time. For the mechanochromic elastomers, the data input requires precisely control the dose of the crosslinkers or phase tuning agents, making the high-throughput data-processing rather challenging. Here we developed a mechanically gated data display by synergizing the mechanochromism of chiral photonic elastomers and optically responsive molecules. Specifically, the reflectance or emission of the dyes/fluorophores could be selectively reflected or transmitted by the elastomers with desired photonic bandgaps, leading to data displays of given color/fluorescence. Mechanically stretching the elastomers can readily tuning their photonic bandgaps over a wide range, thereby notably alternating the corresponding reflection and emission wavelength, and the outcome of displayed data. Relaxing the elastomers rapidly restores the initial data. Moreover, the displayed data varies notably under L- and R-circular polarizer filter, respectively, offering good programmability and multi-dimensional security features. This work represents a unique data protection approach and enables properties unattainable by conventional mechanochromic fluorophores and elastomers. © 2024

Keyword:

Anticounterfeiting Cholesteric liquid crystal Data encryption Elastomer Mechanically gated display

Community:

  • [ 1 ] [Yu X.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 2 ] [Yu X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fujian, Fuzhou, 350002, China
  • [ 3 ] [Yu X.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350002, China
  • [ 4 ] [Liu J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fujian, Fuzhou, 350002, China
  • [ 5 ] [Liu J.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350002, China
  • [ 6 ] [Liu J.]University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049, China
  • [ 7 ] [Wu H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fujian, Fuzhou, 350002, China
  • [ 8 ] [Wu H.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350002, China
  • [ 9 ] [Wu H.]University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049, China
  • [ 10 ] [Dong Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fujian, Fuzhou, 350002, China
  • [ 11 ] [Dong Y.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350002, China
  • [ 12 ] [Dong Y.]University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049, China
  • [ 13 ] [Wu X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fujian, Fuzhou, 350002, China
  • [ 14 ] [Wu X.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350002, China
  • [ 15 ] [Wu X.]University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049, China
  • [ 16 ] [Zheng S.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 17 ] [Zheng S.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fujian, Fuzhou, 350002, China
  • [ 18 ] [Zheng S.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350002, China
  • [ 19 ] [Feng S.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fujian, Fuzhou, 350002, China
  • [ 20 ] [Feng S.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350002, China
  • [ 21 ] [Feng S.]University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049, China
  • [ 22 ] [Huang W.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 23 ] [Huang W.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fujian, Fuzhou, 350002, China
  • [ 24 ] [Huang W.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian, Fuzhou, 350002, China
  • [ 25 ] [Huang W.]University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing, 100049, China

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Source :

Journal of Luminescence

ISSN: 0022-2313

Year: 2024

Volume: 270

3 . 3 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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