A room-temperature phosphorescent metal-organic framework based on proline-tetrazole ligand - Details

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Abstract：

In　this　study,　a　new　compound　1　with　the　formula　as　[Cd((S/R)-ptz)2]n　was　solvothermal　synthesized　from　Cd(II)　salt　and　(S/R)-5-(pyrrolidin-2-yl)-1H-tetrazole　((S/R)-ptzH)　ligand.　Compound　1　exhibits　good　solvent　stability　and　acid-base　stability.　Notably,　1　displays　yellow　room-temperature　phosphorescence　that　can　be　visually　observed　for　approximately　2　s,　marking　a　significant　milestone　in　metal-organic　frameworks　(MOFs)　incorporating　proline-tetrazole　ligand.　©　2024　Elsevier　Inc.

Keyword：

Coordination polymer Crystal structure Metal-organic frameworks (MOFs) Room-temperature phosphorescence (RTP) Stability Tetrazole

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[ 1 ] [Wang M.-G.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 2 ] [Wang M.-G.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 3 ] [Lan J.-J.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 4 ] [Lan J.-J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 5 ] [Li S.-D.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 6 ] [Hao Y.-Z.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 7 ] [Hao Y.-Z.]Fujian Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fujian, Fuzhou, 350007, China
[ 8 ] [Chen S.-M.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 9 ] [Wang F.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China

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Journal of Solid State Chemistry

ISSN： 0022-4596

Year： 2024

Volume： 334

3 . 2 0 0

JCR@2023

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