Efficient catalysis of Knoevenagel condensation by 1D copper-containing heteropolyoxoniobate at room temperature - Details

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A　1D　copper-containing　organic-inorganic　hybrid　heteropolyoxoniobate,　H3[K(H2O)6][K2(H2O)10]2[Cu(en)2(H2O)2][Cu(en)2(Nb6O19Cu(en))2]·24H2O　(HPONb　1),　has　been　synthesized　to　heterogeneously　catalyze　Knoevenagel　condensation　at　room　temperature　with　high　yields　and　cycling　stability.　The　catalyst　presents　the　best　catalytic　activity　for　Knoevenagel　condensation　among　the　polyoxometalates　(POMs)　reported　to　date.　©　2024　The　Royal　Society　of　Chemistry.

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[ 1 ] [Zuo Y.-K.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated-Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 2 ] [Li Y.-R.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated-Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 3 ] [Sun Y.-Q.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated-Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 4 ] [Li X.-X.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated-Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 5 ] [Sun C.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated-Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 6 ] [Zheng S.-T.]Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated-Materials, College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China

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Inorganic Chemistry Frontiers

ISSN： 2052-1553

Year： 2024

6 . 1 0 0

JCR@2023

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