Potential　health　risks　related　to　environmental　endocrine　disruptors　(EEDs)　have　aroused　research　hotspots　at　the　forefront　of　water　treatment　technologies.　Herein,　nitrogen–doped　titanium　dioxide/schwertmannite　nanocomposites　(N–TiO2/SCH)　have　been　successfully　developed　as　heterogeneous　catalysts　for　the　degradation　of　typical　EEDs　via　photo–Fenton　processes.　Due　to　the　sustainable　Fe(III)/Fe(II)　conversion　induced　by　photoelectrons,　as–prepared　N–TiO2/SCH　nanocomposites　exhibit　much　enhanced　efficiency　for　the　degradation　of　bisphenol　A　(BPA;　ca.　100%　within　60　min　under　visible　irradiation)　in　a　wide　pH　range　of　3.0-7.8,　which　is　significantly　higher　than　that　of　the　pristine　schwertmannite　(ca.　74.5%)　or　N–TiO2　(ca.　10.8%).　In　this　photo–Fenton　system,　the　efficient　degradation　of　BPA　is　mainly　attributed　to　the　oxidation　by　hydroxyl　radical　(•OH)　and　singlet　oxygen　(1O2).　Moreover,　the　possible　catalytic　mechanisms　and　reaction　pathway　of　BPA　degradation　are　systematically　investigated　based　on　analytical　and　photoelectrochemical　analyses.　This　work　not　only　provides　a　feasible　means　for　the　development　of　novel　heterogeneous　photo–Fenton　catalysts,　but　also　lays　a　theoretical　foundation　for　the　potential　application　of　mineral–based　materials　in　wastewater　treatment.　©　2023