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author:

Jiang, Yong (Jiang, Yong.) [1] | Liu, Ruizhe (Liu, Ruizhe.) [2] | Xu, Weiwen (Xu, Weiwen.) [3] | Jiao, Zheng (Jiao, Zheng.) [4] | Wu, Minghong (Wu, Minghong.) [5] (Scholars:吴明红) | Chu, Yuliang (Chu, Yuliang.) [6] | Su, Ling (Su, Ling.) [7] | Cao, Hui (Cao, Hui.) [8] | Hou, Ming (Hou, Ming.) [9] | Zhao, Bing (Zhao, Bing.) [10]

Indexed by:

SCIE

Abstract:

A novel graphene-modified LiMnPO4 composite as a performance-improved cathode material for lithium-ion batteries has been prepared with LiH2PO4, Mn(CH3COO)(2)center dot 4H(2)O, and graphite oxide (GO) suspension by spray-drying method. X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and galvanostatic charge-discharge tests are applied to characterize these materials. The structure analysis shows that LiMnPO4 sheets with width of 100-200 nm and thickness of 20-30 nm are attached to the graphene sheets in pieces. The graphene sheets with good electrical conductivity serve as a conducting network for fast electron transfer between the active materials and charge collector, as well as buffered spaces to accommodate the volume expansion/contraction during the discharge/charge process. The electrochemical tests show that the composite cathode material could deliver a capacity of 105.1 mAh/g at 0.05 C in the voltage range of 2.5-4.4 V. Moreover, the cells showed fair good cycle ability over 50 cycles.

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Community:

  • [ 1 ] [Jiang, Yong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 2 ] [Liu, Ruizhe]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 3 ] [Xu, Weiwen]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 4 ] [Jiao, Zheng]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 5 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 6 ] [Zhao, Bing]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 7 ] [Chu, Yuliang]Shanghai Univ, Instrumental Anal & Res Ctr, Shanghai 200444, Peoples R China
  • [ 8 ] [Su, Ling]Shanghai Aerosp Power Technol Co Ltd, Shanghai 201615, Peoples R China
  • [ 9 ] [Cao, Hui]Shanghai Aerosp Power Technol Co Ltd, Shanghai 201615, Peoples R China
  • [ 10 ] [Hou, Ming]Shanghai Aerosp Power Technol Co Ltd, Shanghai 201615, Peoples R China

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Source :

JOURNAL OF MATERIALS RESEARCH

ISSN: 0884-2914

Year: 2013

Issue: 18

Volume: 28

Page: 2584-2589

1 . 8 1 5

JCR@2013

2 . 7 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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