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author:

Zhu, Youcai (Zhu, Youcai.) [1] | Han, Xiaojin (Han, Xiaojin.) [2] | Huang, Zhanggen (Huang, Zhanggen.) [3] | Hou, Yaqin (Hou, Yaqin.) [4] | Guo, Yaoping (Guo, Yaoping.) [5] | Wu, Minghong (Wu, Minghong.) [6] (Scholars:吴明红)

Indexed by:

SCIE

Abstract:

CeO2 modified V2O5/AC catalysts (V-Ce/AC) were synthesized by an ultrasound-assisted impregnation method, and were employed to remove elemental mercury (Hg-0) from simulated coal combustion flue gas at low temperature (100-200 degrees C). The effects of several operation conditions, including the loading of CeO2, reaction temperature, the role of O-2 and stability of the catalysts were all investigated, respectively. The results showed that 1 V-8Ce/AC catalysts had the highest catalytic activity with 98.3% Hg-0 removal efficiency at 150 degrees C. There was synergistic effect on Hg-0 oxidation when V2O5 and CeO2 combined. Characterization by XPS, we found that both lattice oxygen (O-alpha) and chemisorption oxygen (O-beta) contribute to Hg-0 oxidation. Besides, the possible mechanism of Hg-0 removal over the catalysts was proposed, in which the critical steps were the adsorption of Hg-0 and the oxidation of Hg-0 to Hg2+ by the active oxygen on catalysts surface.

Keyword:

Catalytic oxidation Flue gas Mercury V2O5-CeO2/AC

Community:

  • [ 1 ] [Zhu, Youcai]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 2 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 3 ] [Zhu, Youcai]Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China
  • [ 4 ] [Han, Xiaojin]Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China
  • [ 5 ] [Huang, Zhanggen]Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China
  • [ 6 ] [Hou, Yaqin]Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China
  • [ 7 ] [Guo, Yaoping]Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China
  • [ 8 ] [Guo, Yaoping]Univ Chinese Acad Sci, Beijing 100049, Peoples R China

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Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2018

Volume: 337

Page: 741-749

8 . 3 5 5

JCR@2018

1 3 . 4 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 41

SCOPUS Cited Count: 47

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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