High　electron-hole　separation　efficiency　and　wide　spectrum　absorption　are　desired　for　improving　the　photocatalytic　activity.　In　this　research,　we　integrate　plasmonic　Ag/AgCl　with　a　typical　semiconductor-like　metalorganic　framework　MIL-88A(Fe)　to　form　Ag/AgCl@MIL-88A(Fe)　(ACMA)　nanocomposites　by　a　facile　one-pot　solvothermal　method.　The　results　demonstrate　that　ACMA　nanocomposites　not　only　broaden　the　visible-light　absorption　of　MOFs,　but　also　greatly　accelerate　photo-induced　charge　transfer　rate.　EDS　mapping　and　HRTEM　results　suggest　that　Ag/AgCl　is　uniformly　and　densely　dispersed　on　the　surface　of　MOF,　which　is　beneficial　for　charge　flow　and　expedites　the　charge　migration.　By　virtue　of　the　structural　and　compositional　features,　these　unique　ACMA　nanocomposites　perform　excellent　photocatalytic　activity　on　ibuprofen　(IBP)　in　terms　of　high　degradation　efficiency,　high　mineralization　and　excellent　cycling　stability.　ACMA-2　(Fe:Ag　=　2:1)　displays　highly　efficient　photocatalytic　activity　on　IBP　under　visible　light　irradiation,　and　the　corresponding　photo-degradation　rate　is　10.8　and　40.4　folds　higher　than　that　of　MIL-88A(Fe)　and　Ag/AgCl,　respectively.　Total　organic　carbon　(TOC)　removal　of　IBP　photodegradation　reaches　91%　by　the　catalysis　of　ACMA-2.　Combined　with　the　electrochemical　tests,　quencher　experiments　and　analysis　of　related　degradation　products　identified　by　ion　chromatography　(IC)　and　LC-MS-MS,　oxidation　by　superoxide　radicals　(center　dot　O2-)　as　well　as　holes　(h(+))　and　electrons　(e(-))　is　the　dominant　degradation　process　in　the　photocatalytic　degradation　of　IBP.　This　work　provides　a　new　perspective　for　the　preparation　of　environment-stable　and　efficient　MOF-based　photocatalysts　by　steering　charge　flow.