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The interfacial engineering plays an important role in enhancing the electrochemical properties of graphene-based hybrid materials for energy conversion and storage. Herein, we propose a facile interfacial engineering route for achieving a novel type of SnS2/N-doped graphene (SnS2/NG) composite with superior lithium storage capability. Interestingly, the SnS2 particles formed show two totally different morphologies including ultrasmall nanoparticles about 5 nm and ultrathin nanosheets, and they are strongly coupled with nitrogen-doped graphene, giving rise to a unique 0D/2D heterostructure. In the process, the multiple roles of the 3-aminophenol (AP) linker are well identified by combining the experimental results with the theoretical calculations, where a strong interface is successfully constructed between SnS2 and functionalized graphene. The electrochemical test results demonstrate that the as made SnS2/NG composite exhibits a high lithium storage capacity (1101.3 mAh g(-1) at 100 mA g(-1)), superior cycling stability (a capability fading of 0.04% per cycle for 200 cycles at 100 mA g(-1)), as well as a good rate retention. Such a unique hierarchical nanostructure and the strong interfacial interaction between 0D/2D SnS2 and nitrogen-doped graphene highlight the lithium storage performance of SnS2/NG. (C) 2018 Elsevier Inc. All rights reserved.
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JOURNAL OF COLLOID AND INTERFACE SCIENCE
ISSN: 0021-9797
Year: 2019
Volume: 538
Page: 116-124
7 . 4 8 9
JCR@2019
9 . 4 0 0
JCR@2023
JCR Journal Grade:1
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 24
SCOPUS Cited Count: 23
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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