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author:

Li, Zhen (Li, Zhen.) [1] | Wei, Junjie (Wei, Junjie.) [2] | Ren, Jing (Ren, Jing.) [3] | Wu, Xiaomin (Wu, Xiaomin.) [4] | Wang, Liang (Wang, Liang.) [5] | Pan, Dengyu (Pan, Dengyu.) [6] | Wu, Minghong (Wu, Minghong.) [7] (Scholars:吴明红)

Indexed by:

SCIE

Abstract:

Carbon-based flexible fiber-based supercapacitors (FFSCs) are promising power sources for portable and wearable electronics, but their applications are limited by low energy density due to a lower specific capacitance of common carbon materials. We fabricated ternary all-carbon fiber electrodes (N-GQD/GH/CF) with improved electrochemical performance. In this structure, graphene hydrogel (GH) was grown on carbon fibers (CFs) to form a 3D interconnected porous network (GH/CF), and nitrogen-doped graphene quantum dots (N-GQDs) with high pseudocapacitive activity were electrodeposited into the GH/CF network. The ternary N-GQD/GH/CF hybrid electrode delivered a volumetric capacitance of 93.7 F cm(-3) at 20 mA cm(-3), which was around 7 times higher than that of the GH/CF, while the capacitance retention after 5000 cycles reached 87.9%, which was only a little lower than that of the GH/CF electrode (90.2%). It indicates the introduction of N-GQDs drastically improves the capacitance of the FFSCs without sacrificing the cycle stability. All-carbon asymmetric FFSCs were assembled using N-GQD/GH/CF as positive electrode and GH/CF as negative electrode. The assembled FFSCs exhibited a high energy density of 3.6 mW h cm(-3) at power density of 35.6 mW cm(-3) owing to the wider potential window (2 V) and the higher volumetric capacitance as well as excellent flexibility and cycling stability. (C) 2019 Elsevier Ltd. All rights reserved.

Keyword:

Carbon fibers Flexible fiber-based supercapacitors N-doped graphene quantum dots

Community:

  • [ 1 ] [Li, Zhen]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 2 ] [Wei, Junjie]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 3 ] [Ren, Jing]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 4 ] [Wu, Xiaomin]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 5 ] [Wang, Liang]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 201800, Peoples R China
  • [ 6 ] [Pan, Dengyu]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 201800, Peoples R China
  • [ 7 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 201800, Peoples R China

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Source :

CARBON

ISSN: 0008-6223

Year: 2019

Volume: 154

Page: 410-419

8 . 8 2 1

JCR@2019

1 0 . 5 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 59

SCOPUS Cited Count: 61

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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