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author:

Zhou, Yujia (Zhou, Yujia.) [1] | Wang, Zidong (Wang, Zidong.) [2] | Zheng, Chunfang (Zheng, Chunfang.) [3] | Fu, Qun (Fu, Qun.) [4] | Wu, Minghong (Wu, Minghong.) [5] (Scholars:吴明红) | Zhao, Huaping (Zhao, Huaping.) [6] | Lei, Yong (Lei, Yong.) [7]

Indexed by:

SCIE

Abstract:

Nanostructured current collectors have larger specific surface area and short ion/electron transport path, which are highly desirable for supercapacitors applications. Herein, Co0.85Se@NiNPs (Co0.85Se@NiNP) hybrid electrodes are proposed and fabricated, in which NiNP is served as nanostructured current collectors. NiNP has a vertical pore structure and a large specific surface area, which could effectively promote the ion/electron transport efficiency and reduce internal electrical resistance. Compared with Ni foam and Ni foil as current collectors, NiNP enables Co0.85Se@NiNP electrodes show significantly improved specific capacity, rate performance and cycle stability. Finally, an asymmetric supercapacitor device was assembled with Co0.85Se@NiNP hybrid electrode as the binder-free positive electrode and activated carbon (AC) coated on nickel foam as negative electrode. The Co0.85Se@NiNP//AC asymmetric supercapacitors can work in a wide potential window of 0 - 1.6 V with an ultrahigh specific capacity of 182.3 F g(-1) at 1 A g(-1). Most importantly, Co0.85Se@NiNP//AC has a high energy density of 64.81 Wh kg(-1) at 800 W kg(-1) and an outstanding cycle stability of up to 12000 cycles, indicating that Co0.85Se@NiNP electrode has great application potential in supercapacitors. (C) 2021 Elsevier Ltd. All rights reserved.

Keyword:

Asymmetric supercapacitor Co0.85Se Nanostructured current collectors NiNP arrays

Community:

  • [ 1 ] [Zhou, Yujia]Shanghai Univ, Sch Environm & Chem Engn, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 2 ] [Zheng, Chunfang]Shanghai Univ, Sch Environm & Chem Engn, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 3 ] [Fu, Qun]Shanghai Univ, Sch Environm & Chem Engn, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 4 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 5 ] [Wang, Zidong]Tech Univ Ilmenau, Inst Phys, Fachgebiet Angew Nanophys, D-98693 Ilmenau, Germany
  • [ 6 ] [Zhao, Huaping]Tech Univ Ilmenau, Inst Phys, Fachgebiet Angew Nanophys, D-98693 Ilmenau, Germany
  • [ 7 ] [Lei, Yong]Tech Univ Ilmenau, Inst Phys, Fachgebiet Angew Nanophys, D-98693 Ilmenau, Germany
  • [ 8 ] [Wang, Zidong]Tech Univ Ilmenau, IMN MacroNano, D-98693 Ilmenau, Germany
  • [ 9 ] [Zhao, Huaping]Tech Univ Ilmenau, IMN MacroNano, D-98693 Ilmenau, Germany
  • [ 10 ] [Lei, Yong]Tech Univ Ilmenau, IMN MacroNano, D-98693 Ilmenau, Germany

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Source :

CHEMICAL ENGINEERING SCIENCE

ISSN: 0009-2509

Year: 2021

Volume: 247

4 . 8 8 9

JCR@2021

4 . 1 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 7

SCOPUS Cited Count: 7

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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