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author:

Zhu, Guanjia (Zhu, Guanjia.) [1] | Chao, Dongliang (Chao, Dongliang.) [2] | Xu, Weilan (Xu, Weilan.) [3] | Wu, Minghong (Wu, Minghong.) [4] (Scholars:吴明红) | Zhang, Haijiao (Zhang, Haijiao.) [5]

Indexed by:

SCIE

Abstract:

To accelerate the commercial implementation of high-energy batteries, recent research thrusts have turned to the practicality of Si-based electrodes. Although numerous nanostructured Si-based materials with exceptional performance have been reported in the past 20 years, the practical development of high-energy Si-based batteries has been beset by the bias between industrial application with gravimetrical energy shortages and scientific research with volumetric limits. In this context, the microscale design of Si-based anodes with densified microstructure has been deemed as an impactful solution to tackle these critical issues. However, their large-scale application is plagued by inadequate cycling stability. In this review, we present the challenges in Si-based materials design and draw a realistic picture regarding practical electrode engineering. Critical appraisals of recent advances in microscale design of stable Si-based materials are presented, including interfacial tailoring of Si microscale electrode, surface modification of SiOx microscale electrode, and structural engineering of hierarchical microscale electrode. Thereafter, other practical metrics beyond active material are also explored, such as robust binder design, electrolyte exploration, prelithiation technology, and thick-electrode engineering. Finally, we provide a roadmap starting with material design and ending with the remaining challenges and integrated improvement strategies toward Si-based full cells.

Keyword:

3D porous structures full cell intelligent assembly lithium-ion battery microscale Si-based anode practical metrics Si microparticles Si nanoparticle embedded structure SiOx microparticles

Community:

  • [ 1 ] [Zhu, Guanjia]Shanghai Univ, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 2 ] [Xu, Weilan]Shanghai Univ, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 3 ] [Zhang, Haijiao]Shanghai Univ, Inst Nanochem & Nanobiol, Shanghai 200444, Peoples R China
  • [ 4 ] [Chao, Dongliang]Fudan Univ, Lab Adv Mat, Shanghai 200433, Peoples R China
  • [ 5 ] [Wu, Minghong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China

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Source :

ACS NANO

ISSN: 1936-0851

Year: 2021

Issue: 10

Volume: 15

Page: 15567-15593

1 8 . 0 2 7

JCR@2021

1 5 . 8 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 170

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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