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author:

Zhang, Yuanjun (Zhang, Yuanjun.) [1] | Huang, Zhongyi (Huang, Zhongyi.) [2] | Wu, Kuan (Wu, Kuan.) [3] | Yu, Fangfang (Yu, Fangfang.) [4] | Zhu, Ming (Zhu, Ming.) [5] | Wang, Guanyao (Wang, Guanyao.) [6] | Xu, Gang (Xu, Gang.) [7] | Wu, Minghong (Wu, Minghong.) [8] (Scholars:吴明红) | Liu, Hua-Kun (Liu, Hua-Kun.) [9] | Dou, Shi-Xue (Dou, Shi-Xue.) [10] | Wu, Chao (Wu, Chao.) [11]

Indexed by:

SCIE

Abstract:

Metallic Zinc (Zn) has attracted great attention as a promising anode for aqueous batteries owing to its high theoretical capacity, low cost, and high natural abundance. However, Zn anode suffers from a crucial challenge, namely the growth of Zn dendrites, which brings not only a short life span but also severe safety concerns. In this work, we report that anionic tin sulfide nanosheets (TS-Ns) server as electrolyte additive to mitigate the dendrite growth. The negatively charge TS-Ns can attract the positive Zn2+ from the electrolyte through electrostatic interaction and increase the local concentration of Zn2+. Moreover, TS-Ns can co-deposit with Zn2+ at the initial deposition stage and then form an interfacial protection layer around the Zn surface, guiding the uniform deposition of Zn on cycling. The TS-Ns additive endow the Zn anode with excellent performance, reflected by stable cycling for 3700 h in a symmetric cell with a capacity of 0.2 mAh /cm(2) and for 500 cycles in an asymmetric cell with an average coulombic efficiency of 99.6%. These merits bring high capacity and low polarization in Zn parallel to Mno(2) full cells. We believe that TS-Ns additive provides a new pathway to achieve high-performance Zn metal anodes in aqueous electrolytes.

Keyword:

Anionic 2D Nanosheets Co-deposition Dendrite-free Electrolyte additive Zn metal anode

Community:

  • [ 1 ] [Zhang, Yuanjun]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 2 ] [Huang, Zhongyi]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 3 ] [Wu, Kuan]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 4 ] [Wang, Guanyao]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 5 ] [Xu, Gang]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 6 ] [Wu, Chao]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 7 ] [Yu, Fangfang]Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
  • [ 8 ] [Zhu, Ming]Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
  • [ 9 ] [Liu, Hua-Kun]Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
  • [ 10 ] [Dou, Shi-Xue]Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
  • [ 11 ] [Wu, Chao]Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
  • [ 12 ] [Wu, Minghong]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 13 ] [Wu, Minghong]Shanghai Univ, Key Lab Organ Compound Pollut Control Engn MOE, Shanghai 200444, Peoples R China

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Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2021

Volume: 430

1 6 . 7 4 4

JCR@2021

1 3 . 4 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 31

SCOPUS Cited Count: 31

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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