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author:

Fang, Lei (Fang, Lei.) [1] (Scholars:方雷) | Zhou, Jiaqi (Zhou, Jiaqi.) [2] | Yuan, Qiang (Yuan, Qiang.) [3] | Que, Yun (Que, Yun.) [4] (Scholars:阙云) | Chen, Zhen (Chen, Zhen.) [5] | Zhang, Canlin (Zhang, Canlin.) [6] (Scholars:章灿林)

Indexed by:

EI Scopus SCIE

Abstract:

To explore the modification of rheological behavior of fresh cement paste by in situ polymerization, the rheological properties of fresh in situ polymerization modified cement (IPMC) pastes with various acrylamide (AM) monomer dosages and resting time were investigated by rheology test in this paper. The interaction mechanism between inorganic-organic components of IPMC paste and its influence on rheology are also discussed. The results revealed that the yield stress and plastic viscosity of fresh IPMC paste decreased as the AM dosage increased, and rose rapidly with the resting time when the AM dosage was more than 5%. The time-dependent rheological properties of IPMC paste were associated with various periods of AM polymerization reaction. This paper also found that the dispersing effect produced by the AM adsorption and the flocculating effect generated from the polyacrylamide (PAM) microgels bridging would jointly impact the structural buildup of IPMC paste; the former improved the rheological properties and fluidity, while the latter acted contrary. Our results provide the underlying insights needed to guide the dynamic regulation of rheological properties of cement-based materials by in situ polymerization modification.

Keyword:

Acrylamide (AM) monomer Adsorption In situ polymerization Rheological properties Structural buildup

Community:

  • [ 1 ] [Fang, Lei]Fuzhou Univ, Sch Adv Mfg, Quanzhou 362200, Peoples R China
  • [ 2 ] [Zhou, Jiaqi]Fuzhou Univ, Sch Adv Mfg, Quanzhou 362200, Peoples R China
  • [ 3 ] [Yuan, Qiang]Cent South Univ, Sch Civil Engn, Changsha 410075, Peoples R China
  • [ 4 ] [Que, Yun]Fuzhou Univ, Coll Civil Engn, Fuzhou 350116, Peoples R China
  • [ 5 ] [Zhang, Canlin]Fuzhou Univ, Coll Civil Engn, Fuzhou 350116, Peoples R China
  • [ 6 ] [Chen, Zhen]Fujian Commun Planning & Design Inst Co Ltd, Res & Dev Ctr Transport Ind New Mat, Technol Applicat Highway Construct & Maintenance O, Fuzhou 353404, Peoples R China

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Source :

JOURNAL OF MATERIALS IN CIVIL ENGINEERING

ISSN: 0899-1561

Year: 2023

Issue: 12

Volume: 35

3 . 1

JCR@2023

3 . 1 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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