Indexed by:
Abstract:
Pt-based catalysts have been widely investigated in propane dehydrogenation (PDH) owing to their high activity in C-H activation, while it suffers from Pt sintering and coke deposition. We develop a transition metal Fe and zeolite support synergistic-modified method to realize the highly dispersed and stable Pt species inside zeolite over Pt/Fe-silicate-1. And it shows the excellent PDH performance with propylene generation rate of 51.6 mol C3H6 g(Pt)(-1) h(-1) and low deactivation rate constant k(d) of 0.017 h(-1) as well as a high TOFPt of 37.6 s(-1) at 550 & DEG;C. The systematic characterizations reveal the isolated Fe3+ species could significantly improve Pt dispersity and regulate Pt electronic density to realize a more positive Ptd+ species inside Silicalite-1 pore. And the further in situ DRIFTS experiments demonstrate that the synergistic effect between the appropriate acidic Fe sites and the highly dispersed Ptd+ species around Fe species are responsible for the superior PDH performance.
Keyword:
Reprint 's Address:
Email:
Version:
Source :
AICHE JOURNAL
ISSN: 0001-1541
Year: 2023
Issue: 12
Volume: 69
3 . 5
JCR@2023
3 . 5 0 0
JCR@2023
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 5
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
Affiliated Colleges: