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author:

Zhang, Ying (Zhang, Ying.) [1] | Wang, Xiaofang (Wang, Xiaofang.) [2] | Deng, Huihui (Deng, Huihui.) [3] | Sun, Qin (Sun, Qin.) [4] | Li, Baozhen (Li, Baozhen.) [5] | Zheng, Wenchun (Zheng, Wenchun.) [6] | Ren, Zhuangzhuang (Ren, Zhuangzhuang.) [7] | Fang, Xiangqing (Fang, Xiangqing.) [8] | Tan, Li (Tan, Li.) [9] (Scholars:谭理) | Tang, Yu (Tang, Yu.) [10] (Scholars:汤禹) | Wu, Lizhi (Wu, Lizhi.) [11] (Scholars:吴立志)

Indexed by:

EI Scopus SCIE

Abstract:

Pt-based catalysts have been widely investigated in propane dehydrogenation (PDH) owing to their high activity in C-H activation, while it suffers from Pt sintering and coke deposition. We develop a transition metal Fe and zeolite support synergistic-modified method to realize the highly dispersed and stable Pt species inside zeolite over Pt/Fe-silicate-1. And it shows the excellent PDH performance with propylene generation rate of 51.6 mol C3H6 g(Pt)(-1) h(-1) and low deactivation rate constant k(d) of 0.017 h(-1) as well as a high TOFPt of 37.6 s(-1) at 550 & DEG;C. The systematic characterizations reveal the isolated Fe3+ species could significantly improve Pt dispersity and regulate Pt electronic density to realize a more positive Ptd+ species inside Silicalite-1 pore. And the further in situ DRIFTS experiments demonstrate that the synergistic effect between the appropriate acidic Fe sites and the highly dispersed Ptd+ species around Fe species are responsible for the superior PDH performance.

Keyword:

isolated Fe3+ propane dehydrogenation Pt & delta;+ Pt/Fe-S-1 synergistic effect

Community:

  • [ 1 ] [Zhang, Ying]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Wang, Xiaofang]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 3 ] [Deng, Huihui]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 4 ] [Sun, Qin]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 5 ] [Li, Baozhen]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 6 ] [Zheng, Wenchun]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 7 ] [Ren, Zhuangzhuang]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 8 ] [Tan, Li]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 9 ] [Tang, Yu]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 10 ] [Wu, Lizhi]Fuzhou Univ, Inst Mol Catalysis & In Situ Operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 11 ] [Fang, Xiangqing]Xian Aeronaut Univ, Xian, Shaanxi, Peoples R China

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Source :

AICHE JOURNAL

ISSN: 0001-1541

Year: 2023

Issue: 12

Volume: 69

3 . 5

JCR@2023

3 . 5 0 0

JCR@2023

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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