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author:

Wanru Liao (Wanru Liao.) [1] | Suwei Lu (Suwei Lu.) [2] | Weihang Chen (Weihang Chen.) [3] | Shuying Zhu (Shuying Zhu.) [4] (Scholars:祝淑颖) | Yuzhou Xia (Yuzhou Xia.) [5] | Min-Quan Yang (Min-Quan Yang.) [6] | Shijing Liang (Shijing Liang.) [7] (Scholars:梁诗景)

Abstract:

Dye-sensitized photocatalysis has been extensively studied for photocatalytic solar energy conversion due to the advantage in capturing long-wavelength photons with a high absorption coefficient.The rational integration of photosensitizer with semiconductor and cocatalyst to collaboratively operate in one system is highly desired.Here,we fabricate a Ni(OH)2-loaded titanate nanosheet(Ni(OH)2/H2Ti6O13)composite for high-performance dye-sensitized photocatalytic CO2 reduction.The ultrathin H2Ti6O13 nanosheets with negative surface charge provide an excellent support to anchor the dye photosensitizer,while the loaded Ni(OH)2 serves as an adsorbent of CO2 and electron sink of photoelectrons.As such,the photoelectrons derived from the[Ru(bpy)3]Cl2 sensitizer can be targeted transfer to the Ni(OH)2 active sites via the H2Ti6O13 nanosheets linker.A high CO production rate of 1801 μmol g-1 h-1 is obtained over the optimal Ni(OH)2/H2Ti6O13,while the pure H2Ti6O13 shows significantly lower CO2 reduction performance.The work is anticipated to trigger more research attention on the rational design and synthesis of earth-abundant transition metal-based cocatalysts decorated on ultrathin 2D platforms for artificially photocatalytic CO2 reduction.

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Community:

  • [ 1 ] [Shuying Zhu]福州大学
  • [ 2 ] [Min-Quan Yang]College of Environmental Science and Engineering,Fujian Key Laboratory of Pollution Control & Resource Reuse,Fujian Normal University,Fuzhou,350007,China
  • [ 3 ] [Yuzhou Xia]Province University Key Laboratory of Green Energy and Environment Catalysis,Ningde Normal University,Ningde,352100,China
  • [ 4 ] [Wanru Liao]福州大学
  • [ 5 ] [Suwei Lu]College of Environmental Science and Engineering,Fujian Key Laboratory of Pollution Control & Resource Reuse,Fujian Normal University,Fuzhou,350007,China
  • [ 6 ] [Weihang Chen]福州大学
  • [ 7 ] [Shijing Liang]福州大学

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Source :

绿色化学工程(英文)

CN: 10-1713/TQ

Year: 2022

Issue: 3

Volume: 3

Page: 240-249

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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