We　report　a　general　approach　to　highly　functionalized　(Z)-allylic　amines　by　decarboxylative　allylation　of　vinyloxazolidin-2-ones.　This　process　engages　sodium　sulfinates　as　nucleophiles　to　form　a　new　carbon-sulfur　bond,　utilizing　a　palladium　catalyst　generated　from　Pd(OAc)(2)　and　diphosphine　ligand　dpppe.　The　scope　of　the　protocol　is　illustrated　by　the　synthesis　of　30　representative　allylic　amines　with　high　regio-　and　stereoselectivity.　Mechanistic　studies　show　that　the　Z-selectivity　of　the　reaction　stems　from　the　formation　of　a　palladacycle　intermediate　through　Pd-N　chelation.　The　synthetic　utility　of　this　method　was　further　exemplified　by　the　gram-scale　synthesis　and　subsequent　transformations　to　various　compounds.