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author:

Zou, Yuanfeng (Zou, Yuanfeng.) [1] | Yue, Zhongwei (Yue, Zhongwei.) [2] | He, Shuai (He, Shuai.) [3] | Li, Zhishan (Li, Zhishan.) [4] | Chen, Zhiyi (Chen, Zhiyi.) [5] | Ai, Na (Ai, Na.) [6] (Scholars:艾娜) | Sun, Xiao (Sun, Xiao.) [7] | Rickard, William D. A. (Rickard, William D. A..) [8] | Guo, Meiting (Guo, Meiting.) [9] | Jiang, San Ping (Jiang, San Ping.) [10] | Chen, Kongfa (Chen, Kongfa.) [11] (Scholars:陈孔发)

Indexed by:

EI Scopus SCIE

Abstract:

Ruddlesden-Popper oxide La2NiO4+& delta; (LNO) has a high ionic conductivity and good thermalmatch withthe electrolyte of solid oxide fuel cells (SOFCs); however, LNO suffersfrom performance decay owing to the La surface segregation under theoperation conditions of SOFCs. Herein, we report an in situ electrochemicaldecoration strategy to improve the electrocatalytic activity and durabilityof LNO cathodes. We show that the electrochemical polarization leadsto in situ construction of the LNO@Pt core-shell structure,significantly suppressing the detrimental effect of La surface segregationon the LNO cathode. The initial peak power density of a single cellwith the LNO cathode is 0.71 W cm(-2) at 750 & DEG;C,increasing to 1.39 W cm(-2) by the in situ constructionof the LNO@Pt core-shell structure after polarization at 0.5A cm(-2) for 20 h. The LNO@Pt core-shell structureis also highly durable without noticeable performance degradationover the duration of the test for 180 h. The findings shed light onthe design and fabrication of highly active and durable LNO-basedcathodes for SOFCs.

Keyword:

core-shell structure electrochemical polarization La surface segregation LNO solid oxide fuel cells

Community:

  • [ 1 ] [Zou, Yuanfeng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Yue, Zhongwei]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Chen, Zhiyi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Zou, Yuanfeng]Foshan Xianhu Lab Adv Energy Sci & Technol Guangdo, Foshan 528216, Peoples R China
  • [ 6 ] [He, Shuai]Foshan Xianhu Lab Adv Energy Sci & Technol Guangdo, Foshan 528216, Peoples R China
  • [ 7 ] [Li, Zhishan]Foshan Xianhu Lab Adv Energy Sci & Technol Guangdo, Foshan 528216, Peoples R China
  • [ 8 ] [Guo, Meiting]Foshan Xianhu Lab Adv Energy Sci & Technol Guangdo, Foshan 528216, Peoples R China
  • [ 9 ] [Jiang, San Ping]Foshan Xianhu Lab Adv Energy Sci & Technol Guangdo, Foshan 528216, Peoples R China
  • [ 10 ] [Ai, Na]Fuzhou Univ, Fujian Coll Assoc Instrumental Anal Ctr, Fuzhou 350108, Fujian, Peoples R China
  • [ 11 ] [Sun, Xiao]Curtin Univ, John De Laeter Ctr, Perth, WA 6102, Australia
  • [ 12 ] [Rickard, William D. A.]Curtin Univ, John De Laeter Ctr, Perth, WA 6102, Australia
  • [ 13 ] [Jiang, San Ping]Curtin Univ, WA Sch Mines Minerals Energy & Chem Engn, Perth, WA 6102, Australia

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Source :

ACS APPLIED MATERIALS & INTERFACES

ISSN: 1944-8244

Year: 2023

8 . 5

JCR@2023

8 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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