Stimuli-responsive　luminescence　plays　a　crucial　role　in　the　development　of　mechanoluminescent　materials.　Here,　we　designed　and　synthesized　four　o-carborane-based　aggregation-induced　emission　molecules,　two　of　which,　CB-Ph-P　and　CB-Ph-PAn,　exhibited　multiple　solid-state　fluorescence　emissions.　Upon　mechanical　stimulation,　the　recrystallization　solid　of　CB-Ph-P　caused　a　bathochromic　shift　in　its　fluorescence　emission　from　423　nm　to　608　nm.　Similarly,　CB-Ph-PAn　exhibits　a　transition　in　the　fluorescence　emission　wavelength　from　393　nm　to　623　nm　when　in　the　solid　state.　In　order　to　gain　insight　into　the　mechanism　behind　their　luminescence　behavior,　we　performed　analyses　including　powder　X-ray　diffraction,　photophysical　properties,　thermal　properties,　and　single-crystal　structure　analysis.　It　is　deemed　that　the　polymorphism　may　be　related　to　different　weak　interactions,　packing　modes　and　torsion　angles.