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author:

He, Yongsheng (He, Yongsheng.) [1] | Deng, Huihui (Deng, Huihui.) [2] | Zhang, Ying (Zhang, Ying.) [3] | Wang, Xiaofang (Wang, Xiaofang.) [4] | Zheng, Wenchun (Zheng, Wenchun.) [5] | Ren, Zhuangzhuang (Ren, Zhuangzhuang.) [6] | Tan, Li (Tan, Li.) [7] (Scholars:谭理) | Tang, Yu (Tang, Yu.) [8] (Scholars:汤禹) | Wu, Lizhi (Wu, Lizhi.) [9] (Scholars:吴立志)

Indexed by:

EI Scopus SCIE

Abstract:

Utilizing the confinement effect of zeolite pores to stabilize active sites has been developed for the improvement of catalytic stability and performance. Herein, a facile strategy is proposed to synthesize a Sn stabilizing dispersed Pt delta+ sites confined in zeolite pore catalyst via Ar calcination for propane dehydrogenation (PDH). 0.2Pt/0.5Sn-S-1-Ar shows excellent propylene formation rate of 10.0 mol C3H6 center dot g(Pt)(-1)center dot h(-1) and propylene selectivity higher than 99.5% at 450 degrees C, and the superior catalyst stability in 200 h on-stream. And it has the lowest apparent activation energy barrier of 18.45 KJ/mol over Pt-based catalyst for PDH to our knowledge. According to systemic characterizations, it is demonstrated that the implantation of Sn into Silicalite-1 framework before introducing Pt is essential to generate the highly dispersed Pt delta+ species confined in zeolite pore, and the Pt delta+ species confined in zeolite pore with stronger propane adsorption and propylene desorption ability is responsible for superior PDH performance.

Keyword:

Confinement effect Low activation energy Low temperature Propane dehydrogenation Pt/Sn-S-1

Community:

  • [ 1 ] [He, Yongsheng]Fuzhou Univ, Inst Mol Catalysis & In situ operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Deng, Huihui]Fuzhou Univ, Inst Mol Catalysis & In situ operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zhang, Ying]Fuzhou Univ, Inst Mol Catalysis & In situ operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 4 ] [Wang, Xiaofang]Fuzhou Univ, Inst Mol Catalysis & In situ operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 5 ] [Zheng, Wenchun]Fuzhou Univ, Inst Mol Catalysis & In situ operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 6 ] [Ren, Zhuangzhuang]Fuzhou Univ, Inst Mol Catalysis & In situ operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 7 ] [Tan, Li]Fuzhou Univ, Inst Mol Catalysis & In situ operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 8 ] [Tang, Yu]Fuzhou Univ, Inst Mol Catalysis & In situ operando Studies, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 9 ] [Wu, Lizhi]Fuzhou Univ, Inst Mol Catalysis & In situ operando Studies, Coll Chem, Fuzhou 350108, Peoples R China

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Source :

FUEL

ISSN: 0016-2361

Year: 2023

Volume: 352

6 . 7

JCR@2023

6 . 7 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:35

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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