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author:

Chen, H.-Y. (Chen, H.-Y..) [1] | Chen, Z.-Y. (Chen, Z.-Y..) [2] | Mao, M. (Mao, M..) [3] | Wu, Y.-Y. (Wu, Y.-Y..) [4] | Yang, F. (Yang, F..) [5] | Gong, L.-X. (Gong, L.-X..) [6] | Zhao, L. (Zhao, L..) [7] | Cao, C.-F. (Cao, C.-F..) [8] | Song, P. (Song, P..) [9] | Gao, J.-F. (Gao, J.-F..) [10] | Zhang, G.-D. (Zhang, G.-D..) [11] | Shi, Y.-Q. (Shi, Y.-Q..) [12] | Cao, K. (Cao, K..) [13] | Tang, L.-C. (Tang, L.-C..) [14]

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Scopus

Abstract:

Polydimethylsiloxanes (PDMS) foam as one of next-generation polymer foam materials shows poor surface adhesion and limited functionality, which greatly restricts its potential applications. Fabrication of advanced PDMS foam materials with multiple functionalities remains a critical challenge. In this study, unprecedented self-adhesive PDMS foam materials are reported with worm-like rough structure and reactive groups for fabricating multifunctional PDMS foam nanocomposites decorated with MXene/cellulose nanofiber (MXene/CNF) interconnected network by a facile silicone foaming and dip-coating strategy followed by silane surface modification. Interestingly, such self-adhesive PDMS foam produces strong interfacial adhesion with the hybrid MXene/CNF nano-coatings. Consequently, the optimized PDMS foam nanocomposites have excellent surface super-hydrophobicity (water contact angle of ≈159o), tunable electrical conductivity (from 10−8 to 10 S m−1), stable compressive cyclic reliability in both wide-temperature range (from −20 to 200 oC) and complex environments (acid, sodium, and alkali conditions), outstanding flame resistance (LOI value of >27% and low smoke production rate), good thermal insulating performance and reliable strain sensing in various stress modes and complex environmental conditions. It provides a new route for the rational design and development of advanced PDMS foam nanocomposites with versatile multifunctionalities for various promising applications such as intelligent healthcare monitoring and fire-safe thermal insulation. © 2023 Wiley-VCH GmbH.

Keyword:

multifunctionality MXene-based coating silicone foams surfaces and interfaces

Community:

  • [ 1 ] [Chen H.-Y.]College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Hangzhou Normal University, Hangzhou, 311121, China
  • [ 2 ] [Chen Z.-Y.]College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Hangzhou Normal University, Hangzhou, 311121, China
  • [ 3 ] [Mao M.]College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Hangzhou Normal University, Hangzhou, 311121, China
  • [ 4 ] [Mao M.]Laboratory and Equipment Management Office, Nanjing Normal University, Nanjing, 210023, China
  • [ 5 ] [Wu Y.-Y.]College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Hangzhou Normal University, Hangzhou, 311121, China
  • [ 6 ] [Yang F.]College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Hangzhou Normal University, Hangzhou, 311121, China
  • [ 7 ] [Gong L.-X.]College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Hangzhou Normal University, Hangzhou, 311121, China
  • [ 8 ] [Zhao L.]College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Hangzhou Normal University, Hangzhou, 311121, China
  • [ 9 ] [Cao C.-F.]Centre for Future Materials, University of Southern Queensland, Springfield, 4300, Australia
  • [ 10 ] [Song P.]Centre for Future Materials, University of Southern Queensland, Springfield, 4300, Australia
  • [ 11 ] [Song P.]School of Agriculture and Environmental Science, University of Southern Queensland, Springfield, 4300, Australia
  • [ 12 ] [Gao J.-F.]College of Chemistry and Chemical Engineering, Yangzhou University, Jiangsu, Yangzhou, 225002, China
  • [ 13 ] [Zhang G.-D.]College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Hangzhou Normal University, Hangzhou, 311121, China
  • [ 14 ] [Shi Y.-Q.]College of Environment and Safety Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 15 ] [Cao K.]State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, China
  • [ 16 ] [Tang L.-C.]College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of MoE, Hangzhou Normal University, Hangzhou, 311121, China

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Source :

Advanced Functional Materials

ISSN: 1616-301X

Year: 2023

Issue: 48

Volume: 33

1 8 . 5

JCR@2023

1 8 . 5 0 0

JCR@2023

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 67

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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