From a new trigonal cadmium hexacyanoferrate to a Cd Prussian Blue analogue: single-crystal to single-crystal transformation and C2H2/CO2 separation capability - Details

author：

Ou, Y. (Ou, Y..) ^[1] | Liang, Z. (Liang, Z..) ^[2] | Ju, Z. (Ju, Z..) ^[3] | Yuan, D.Q. (Yuan, D.Q..) ^[4]

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Abstract：

A　newly　synthesized　coordination　polymer,　[Cd(DMSO)(H2O)]3[Fe(CN)6]2　(CdHCF-T),　based　on　Cd2+　and　Fe(CN)63−　ions　was　prepared　in　a　DMSO/H2O　mixed　solution　and　crystalized　in　the　trigonal　space　group　P-31c.　This　novel　3D　structure　presented　an　interesting　single-crystal　to　single-crystal　transformation　when　the　coordinated　DMSO　molecules　were　replaced　by　H2O,　forming　a　well-known　Cd　Prussian　Blue　analogue　(Cd-PBA).　This　occurrence　is　a　rare　phenomenon　in　transition　metal　hexacyanometallates　and　may　provide　a　new　strategy　for　obtaining　new　structures　and　overcoming　the　difficulty　of　growing　single　crystals　of　Prussian　Blue　analogues.　Subsequent　gas　sorption　and　separation　investigations　based　on　the　obtained　Cd-PBA　were　also　carried　out　to　evaluate　its　C2H2/CO2　separation　capability.　©　2023　Wiley-VCH　GmbH.

Keyword：

cadmium hexacyanoferrate gas separation Prussian Blue analogue single crystal transformation

Community：

[ 1 ] [Ou Y.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Ou Y.]State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 3 ] [Ou Y.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
[ 4 ] [Liang Z.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Liang Z.]State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 6 ] [Liang Z.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
[ 7 ] [Ju Z.]State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 8 ] [Yuan D.Q.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 9 ] [Yuan D.Q.]State Key Lab of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 10 ] [Yuan D.Q.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China

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From a new trigonal cadmium hexacyanoferrate to a Cd Prussian Blue analogue: single-crystal to single-crystal transformation and C2H2/CO2 separation capability
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Source ：

Zeitschrift fur Anorganische und Allgemeine Chemie

ISSN： 0044-2313

Year： 2023

Issue： 15

Volume： 649

1 . 1

JCR@2023

1 . 1 0 0

JCR@2023

ESI HC Threshold：39

JCR Journal Grade：4

CAS Journal Grade：4

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ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 2

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