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Abstract:
A novel electrolysis-integrated anammox (Ele-anammox) process was developed for intensified nitrogen removal and concomitant phosphorus recovery from nutrient-rich wastewater. By conducting a parallel experiment, average removal efficiencies of total nitrogen (TN) and total phosphorus (TP) in Ele-anammox reactor reached 90.69% and 95.02% respectively, showing increases of 7.76% and 79.08%, as compared to the traditional anammox process. Anammox reaction and synergetic denitrification were mainly responsible for the reinforced N-removal. Successions of microbial communities revealed that Candidatus Kuenenia declined markedly while Candidatus Brocadia was enriched in Ele-anammox system, suggesting that electrical environment provided Candidatus Brocadia with a competitive advantage over other anammox bacteria. Based on the proposed current control strategy (the applied current was calculated to match the influent P loading), precise release of soluble Fe2+ could be achieved by anodic oxidation. Various elemental analysis methods, including the standards, measurements and testing (SMT) protocol, energy dispersive X-ray spectroscopy (eSEM-EDX), X-ray fluorescence spectrometry (XRF) and inductively coupled plasma emission spectroscopy (ICP-OES), jointly indicated that the solid phase of Ele-anammox was primarily Fe-P precipitation, which showed a similar Fe:P ratio with vivianite (Fe-3(PO4)(2)center dot 8H(2)O, 1.5). X-ray diffraction (XRD) analysis further validated the in-situ crystallization of vivianite, and semi-quantification implied a vivianite content of 85%. Mossbauer spectroscopy showed at least 51.48% similar to 59.11% of iron was bound in vivianite, while impurity occupation and potential oxidization may impair the purity of P-recovery products, which should be concerned in future practice.
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CHEMICAL ENGINEERING JOURNAL
ISSN: 1385-8947
Year: 2023
Volume: 466
1 3 . 4
JCR@2023
1 3 . 4 0 0
JCR@2023
ESI Discipline: ENGINEERING;
ESI HC Threshold:35
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 5
SCOPUS Cited Count: 6
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: