Visible-Light-Induced Paternò-Büchi Reaction of Anthraquinones for the Synthesis of Spirocyclic Oxetanes - Details

author：

Xu, X. (Xu, X..) ^[1] | Yang, F. (Yang, F..) ^[2] | Zhang, X. (Zhang, X..) ^[3] | Gao, Y. (Gao, Y..) ^[4] | Su, W. (Su, W..) ^[5]

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Abstract：

Reported　here　is　a　general　visible-light-induced　Paternò-Büchi　reaction　between　anthraquinones　and　olefins　lead　to　the　formation　of　diverse　anthraquinone-based　spirocyclic　oxetanes　which　served　as　an　important　scaffold　in　natural　drugs　and　products.　This　approach　negates　the　need　for　UV　light,　thus　overcome　the　synthetic　limitations　of　the　traditional　Paternò-Büchi　reaction.　Therefore,　the　method　reported　here　is　characterized　by　high　regioselectivity,　simple　operations,　mild　conditions　and　broad　scope.　©　2023　Wiley-VCH　GmbH.

Keyword：

[2+2] photocycloaddition anthraquinones Paternò-Büchi Reaction spirocyclic oxetanes visible-light-induced

Community：

[ 1 ] [Xu X.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 2 ] [Xu X.]State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, 350002, China
[ 3 ] [Yang F.]State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, 350002, China
[ 4 ] [Yang F.]University of Chinese Academy of Sciences, Beijing, 100049, China
[ 5 ] [Zhang X.]State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, 350002, China
[ 6 ] [Gao Y.]State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, 350002, China
[ 7 ] [Su W.]State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao Road West, Fuzhou, 350002, China
[ 8 ] [Su W.]University of Chinese Academy of Sciences, Beijing, 100049, China

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Related Keywords：

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Source ：

Asian Journal of Organic Chemistry

ISSN： 2193-5807

Year： 2023

Issue： 5

Volume： 12

2 . 8

JCR@2023

2 . 8 0 0

JCR@2023

ESI HC Threshold：39

JCR Journal Grade：1

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 8

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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