Metal-organic　frameworks　(MOFs)　are　with　extensive　attention　for　environmental　remediation　due　to　their　various　modification　and　high　density　of　active　sites.　Herein,　a　series　of　Ag/ZnO@ZIF-C　with　core-shell　structure　and　graphene　carbon　(C)　acts　as　a　sandwich　bridge　were　designed　as　a　photocatalyst,　accelerating　the　interfacial　charge　transfer　rate　between　Ag　and　ZnO.　Photocatalytic　activities　of　Ag/ZnO@ZIF-C　is　remarkably　improved　toward　rhodamine　B　(RhB)　under　UV　irradiation,　i.e.,　the　degradation　rate　by　Ag/ZnO@ZIF-C　(20　wt%)　is　2.27　times　than　that　of　P25.　RhB　molecules　were　simultaneously　photodegraded　at　multiple　sites,　including　N-site　deethyl,　conjugate　structure　and　benzene　ring.　The　photocatalytic　upgrading　performance　was　recognized　to　the　synergetic　interface　between　ZnO@ZIF-C　and　Ag　nanoparticles　(NPs)　with　effective　separation　and　suppressed　the　recombination　of　electrons　and　holes.　It　is　suggesting　that　the　electrons　in　the　valence　band　(VB)　of　ZnO　are　excited　to　the　conduction　band　(CB)　and　transferred　to　Ag　NPs　through　the　ZIF-C　layer,　then　react　with　adsorbed　oxygen　to　create　superoxide　radicals　and　degrade　RhB　into　small　molecules.　After　a　five-consecutive　operation,　its　photocatalytic　efficiency　by　Ag/ZnO@ZIF-C　(20　wt%)　still　maintains　at　95.11　%.　This　work　provides　a