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author:

Xiang, Jingjing (Xiang, Jingjing.) [1] | Hao, Youchen (Hao, Youchen.) [2] | Gao, Yuting (Gao, Yuting.) [3] | Ji, Lei (Ji, Lei.) [4] | Wang, Li (Wang, Li.) [5] | Sun, Guoxing (Sun, Guoxing.) [6] | Tang, Yuxin (Tang, Yuxin.) [7] | Zhu, Yaofeng (Zhu, Yaofeng.) [8] | Jiang, Yinzhu (Jiang, Yinzhu.) [9]

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EI

Abstract:

Iron hexacyanoferrate (FeHCF) is regarded as a promising cathode material of sodium-ion batteries (SIBs) due to the merits of easy preparation, low cost and three-dimensional open framework. However, the practical application of FeHCF is highly restricted by the intrinsic [Fe(CN)6]4- vacancy and coordinated water as well as nanoscale particles. Herein, sodium citrate is introduced to mediate the drawbacks of FeHCF, resulting in microscale particles with less water content. Accordingly, the modified sample, FeHCF-3, achieved the performance of 92 mA h g−1 at 100 mA g−1 and 80 % capacity retention after 300 cycles. Furthermore, an optimal iron hexacyanoferrate (FeHCF-H-2) with high-salt-concentration preparation is designed and performs a good reversibility of 96 mA h g−1 after 700 cycles at 100 mA g−1. Such strategy may drive the application of high-tap, low-defect and stable cathode for SIBs. © 2023 Elsevier B.V.

Keyword:

Cathodes Iron Iron compounds Metal ions Sodium compounds Sodium-ion batteries

Community:

  • [ 1 ] [Xiang, Jingjing]School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou; 310018, China
  • [ 2 ] [Hao, Youchen]School of Materials Science and Engineering, ZJU-Hangzhou Global Scientific and Technological Innovation Centre, Zhejiang University, Hangzhou; 310027, China
  • [ 3 ] [Gao, Yuting]School of Materials Science and Engineering, ZJU-Hangzhou Global Scientific and Technological Innovation Centre, Zhejiang University, Hangzhou; 310027, China
  • [ 4 ] [Ji, Lei]State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou Research Institute of Rare Earths, Baotou; 014030, China
  • [ 5 ] [Wang, Li]State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou Research Institute of Rare Earths, Baotou; 014030, China
  • [ 6 ] [Sun, Guoxing]Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Macau SAR, Taipa, China
  • [ 7 ] [Tang, Yuxin]College of Chemical Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 8 ] [Zhu, Yaofeng]School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou; 310018, China
  • [ 9 ] [Jiang, Yinzhu]School of Materials Science and Engineering, ZJU-Hangzhou Global Scientific and Technological Innovation Centre, Zhejiang University, Hangzhou; 310027, China
  • [ 10 ] [Jiang, Yinzhu]State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou Research Institute of Rare Earths, Baotou; 014030, China

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Source :

Journal of Alloys and Compounds

ISSN: 0925-8388

Year: 2023

Volume: 946

5 . 8

JCR@2023

5 . 8 0 0

JCR@2023

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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