Electrochemical Synthesis of Benzo[d]imidazole via Intramolecular C(sp3)-H Amination - Details

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An　electrochemical　dehydrogenative　amination　for　the　synthesis　of　benzimidazoles　was　developed.　This　electrosynthesis　method　could　address　the　limitations　of　the　C(sp3)-H　intramolecular　amination　synthesis　reaction　and　provide　novel　access　to　obtain　1,2-disubstituted　benzimidazoles　without　transition　metals　and　oxidants.　Under　undivided　electrolytic　conditions,　various　benzimidazole　derivatives　could　be　synthesized,　exhibiting　functional　group　tolerance.　©　2021　American　Chemical　Society.

Keyword：

Amination Amines Transition metals

Community：

[ 1 ] [Li, An]Province Key Laboratory for Fine Petrochemical Catalysis and Separation, College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Hunan, Yueyang; 414000, China
[ 2 ] [Li, Caohui]Province Key Laboratory for Fine Petrochemical Catalysis and Separation, College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Hunan, Yueyang; 414000, China
[ 3 ] [Yang, Tao]Province Key Laboratory for Fine Petrochemical Catalysis and Separation, College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Hunan, Yueyang; 414000, China
[ 4 ] [Yang, Zan]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou; 350108, China
[ 5 ] [Liu, Yu]Province Key Laboratory for Fine Petrochemical Catalysis and Separation, College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Hunan, Yueyang; 414000, China
[ 6 ] [Li, LiJun]Province Key Laboratory for Fine Petrochemical Catalysis and Separation, College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Hunan, Yueyang; 414000, China
[ 7 ] [Tang, KeWen]Province Key Laboratory for Fine Petrochemical Catalysis and Separation, College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Hunan, Yueyang; 414000, China
[ 8 ] [Zhou, Congshan]Province Key Laboratory for Fine Petrochemical Catalysis and Separation, College of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Hunan, Yueyang; 414000, China

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Source ：

Journal of Organic Chemistry

ISSN： 0022-3263

Year： 2023

Issue： 4

Volume： 88

Page： 1928-1935

3 . 4

JCR@2023

3 . 4 0 0

JCR@2023

ESI HC Threshold：39

JCR Journal Grade：1

CAS Journal Grade：2

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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