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author:

Lin, S.-W. (Lin, S.-W..) [1] | Tong, M.-H. (Tong, M.-H..) [2] | Chen, Y.-X. (Chen, Y.-X..) [3] | Chen, R. (Chen, R..) [4] | Zhao, H.-P. (Zhao, H.-P..) [5] | Jiang, X. (Jiang, X..) [6] | Yang, K. (Yang, K..) [7] | Lu, C.-Z. (Lu, C.-Z..) [8]

Indexed by:

Scopus

Abstract:

Composite of rare earth oxides with TiO2 nanotube arrays can effectively modify the photoelectrochemical (PEC) behavior of TiO2. A CeO2/TiO2 heterojunction was prepared by loading CeO2 nanoparticles on anodized TiO2 nanotube (TNT) arrays for PEC water splitting. The CeO2/TNT electrode exhibited a high photocurrent density of 2.11 mA·cm-2, 4.3 times that of pure TNT (0.49 mA·cm-2) at 1.23 V vs RHE under AM 1.5G light. And CeO2/TNT realized a high PEC H2 evolution rate of 17.86 μmol/h, 4.5 times that of pure TNT at 1.55 V vs RHE. The effective performance of the CeO2/TNT electrode could be attributed to its reasonable band gap structure facilitating visible light absorption and efficient charge transfer, inhibiting the recombination of electron/hole pairs. This work confirms the successful construction of CeO2/TiO2 heterojunction on TNT arrays for improving the PEC performance of TiO2 for H2 production. © 2023 American Chemical Society.

Keyword:

CeO2/TiO2 heterojunction hydrogen production photoelectrochemical water splitting TiO2 nanotube arrays visible light

Community:

  • [ 1 ] [Lin, S.-W.]School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Jiangxi, Ganzhou, 341000, China
  • [ 2 ] [Lin, S.-W.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 3 ] [Lin, S.-W.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 4 ] [Lin, S.-W.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 5 ] [Tong, M.-H.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 6 ] [Tong, M.-H.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 7 ] [Tong, M.-H.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 8 ] [Tong, M.-H.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 9 ] [Chen, Y.-X.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 10 ] [Chen, Y.-X.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 11 ] [Chen, Y.-X.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 12 ] [Chen, Y.-X.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 13 ] [Chen, R.]School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Jiangxi, Ganzhou, 341000, China
  • [ 14 ] [Chen, R.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 15 ] [Chen, R.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 16 ] [Chen, R.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 17 ] [Zhao, H.-P.]School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Jiangxi, Ganzhou, 341000, China
  • [ 18 ] [Zhao, H.-P.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 19 ] [Zhao, H.-P.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 20 ] [Zhao, H.-P.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 21 ] [Jiang, X.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 22 ] [Jiang, X.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 23 ] [Jiang, X.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 24 ] [Yang, K.]School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Jiangxi, Ganzhou, 341000, China
  • [ 25 ] [Lu, C.-Z.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 26 ] [Lu, C.-Z.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 27 ] [Lu, C.-Z.]Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare-Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, 361021, China
  • [ 28 ] [Lu, C.-Z.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China

Reprint 's Address:

  • [Chen, Y.-X.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, China;;[Yang, K.]School of Chemistry and Chemical Engineering, Jiangxi, China;;[Lu, C.-Z.]CAS Key Laboratory of Design and Assembly of Functional Nanostructures, China

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Source :

ACS Applied Energy Materials

ISSN: 2574-0962

Year: 2023

Issue: 2

Volume: 6

Page: 1093-1102

5 . 5

JCR@2023

5 . 5 0 0

JCR@2023

ESI HC Threshold:49

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 43

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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