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author:

Zhan, Y. (Zhan, Y..) [1] | Qiu, B. (Qiu, B..) [2] | Lin, Z. (Lin, Z..) [3] | Guo, L. (Guo, L..) [4]

Indexed by:

Scopus

Abstract:

In this work, sulfhydryl functionalized carbon dots (SH-CDs) were synthesized for the first time by a two-step hydrothermal method. The sulfhydryl group in SH-CDs can be converted efficiently and reversibly in a few minutes under redox conditions. On this basis, ochratoxin A (OTA) induced hybrid chain reaction amplification and alkaline phosphatase enzymatic hydrolysis to produce ascorbic acid (AA). AA reduced the aggregated SH-CDs, thereby realizing the dual-mode rapid quantitative analysis of the OTA concentration by measuring the changes in the fluorescence intensity and absorbance of the SH-CDs solution. The proposed sensor has a good linear relationship with the OTA concentration in the range of 2.0–5.0 nM, and the lowest detection limit is 2.0 nM. Additionally, the visual color change of the solution can improve the simplicity and accuracy of semi-quantitative detection of OTA with the naked eye. In short, this method has the advantages of rapidity, sensitivity, reversibility and visualization. © 2023 Elsevier B.V.

Keyword:

Carbon dot Hybrid chain reaction Ochratoxin A Redox Reversible Sulfhydryl group

Community:

  • [ 1 ] [Zhan, Y.]Jiaxing Key Laboratory of Molecular Recognition and Sensing, College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, 314001, China
  • [ 2 ] [Zhan, Y.]Department of Chemistry, State Key Laboratory of Molecular Engineering of Polymers and Chem, Fudan University, Shanghai, 200433, China
  • [ 3 ] [Qiu, B.]MOE Key Laboratory for Analytical Science of Food Safety and Biology, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Lin, Z.]MOE Key Laboratory for Analytical Science of Food Safety and Biology, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Guo, L.]Jiaxing Key Laboratory of Molecular Recognition and Sensing, College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, 314001, China

Reprint 's Address:

  • [Zhan, Y.]Jiaxing Key Laboratory of Molecular Recognition and Sensing, China;;[Guo, L.]Jiaxing Key Laboratory of Molecular Recognition and Sensing, China

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Source :

Sensors and Actuators B: Chemical

ISSN: 0925-4005

Year: 2023

Volume: 385

6 . 3 9 3

JCR@2018

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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