Special　wettability　endows　surface　anti-fogging　performance　on　transparent　substrates　by　promoting　filmwise　condensation　via　hydrophilic　materials　or　preventing　water　adhesion　via　hydrophobic　materials.　However,　the　harsh　environments　associated　with　low　temperature　and　mechanical　loads　restrict　their　anti-fogging　persistence.　In　this　work,　a　hydrophilic　coating　with　long-lasting　anti-fogging,　anti-freezing,　and　anti-aging　properties　was　rationally　prepared　by　constructing　a　double-layer　structure.　The　bottom　layer　(T　coating)　adopts　a　titanium　dioxide　coating　obtained　by　hydrolysis　of　tetrabutyl　titanate,　which　can　act　as　a　UV　absorber　and　improve　the　UV-shielding　property　of　the　coating.　The　top　layer　(ZGS　coating)　is　constructed　of　a　cross-linked　network　structure　with　zein,　gelatin,　glucose　and　silica　for　anti-freezing　and　anti-fogging　properties.　The　resulting　coating　(ZGST)　can　maintain　excellent　anti-fogging　performance　after　placing　in　a　hot　fog　environment　(100)　for　1　h,　300　cycles　abrasion,　70　tape-peeling,　120　min　ultrasonication　and　extended　service　time　(261　days　so　for).　One　application　of　greenhouse　films　with　anti-fogging　performance　was　demonstrated,　which　can　improve　the　status　quo　of　agricultural　film　and　has　important　significance　for　the　field　of　agricultural　development.　It　is　anticipated　that　this　work　may　offer　valuable　guidance　for　the　preparation　of　anti-fogging,　anti-freezing　and　UV　resistant　optical　materials,　which　allows　potential　applications　in　vehicles,　medical,　agricultural　or　vision　systems　under　extreme　environments.　©　2023　Elsevier　B.V.