Advanced　electrode　design　is　critical　for　the　rapid　development　of　flexible　energy　storage　devices　(ESD)　in　the　emerging　field　of　flexible　electronics.　Metal-organic　frameworks　((MOFs)　for　lithium　storage　have　at-tracted　considerable　attention.　However,　one　of　the　main　obstacles　is　their　poor　electronic　conductivity,　which　restricts　their　cycling　stability　under　redox　conditions.　Herein,　we　report　a　facile　synthesis　route　to　fabricate　Ni(BDC-NH2)/reduced　graphene　oxide　(rGO)　composites　employing　the　solvothermal　method.　Ni　(BDC-NH2)　MOFs　exhibited　a　unique　laminar　and　porous　morphology,　which　helps　with　Li-ion　diffusion,　and　thus　enables　faster　electrode　activation　and　capacitive　controlled　electrochemical　activity.　When　freestanding　Ni(BDC-NH2)/reduced　graphene　oxide　(rGO)　composite　electrode　was　prepared　via　simple　vacuum　filtration.　As　anode　material　for　lithium-ion　batteries.　It　delivered　a　reversible　capacity　of　813　mAh　g-1　at　a　current　density　of　200　mA　g-1　after　100　cycles.　More　importantly,　it　also　shows　an　excellent　rate　of　performance　compared　to　Ni(BDC)/rGO　MOFs.　The　better　electrochemical　performance　of　Ni(BDC-NH2)/rGO　is　attributed　to　the　unique　chain　network　formed　by　the　synergistic　effect　of　multi-coordination　of　car-boxylic　oxygen　and　amino　nitrogen　with　high　theoretical　capacities　and　rGO　with　high　electrical　con-ductivity.　(c)　2022　Published　by　Elsevier　B.V.