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author:

Qi, Qingchun (Qi, Qingchun.) [1] | Xian, Kaihu (Xian, Kaihu.) [2] | Ke, Huizhen (Ke, Huizhen.) [3] | Wu, Junjiang (Wu, Junjiang.) [4] | Zhou, Kangkang (Zhou, Kangkang.) [5] | Gao, Mengyuan (Gao, Mengyuan.) [6] | Liu, Junwei (Liu, Junwei.) [7] | Li, Saimeng (Li, Saimeng.) [8] | Zhao, Wenchao (Zhao, Wenchao.) [9] | Chen, Zheng (Chen, Zheng.) [10] | Ye, Long (Ye, Long.) [11]

Indexed by:

EI SCIE

Abstract:

The past decade has witnessed the prosperity of organic photovoltaic cells (OPVs). In addition to efficiency and cost, stability is another challenge that OPVs face in their practical application. Continuous thermal stress often accelerates the crystallization and phase separation of active layers, leading to a decreased photovoltaic performance. Developing simple and effective strategies to prolong the lifetime of OPVs under heating has attracted increasing attention. In this work, an unexplored random copolymer named PY was incorporated as a high-temperature-resistant aid to the emerging nonfullerene OPVs to control and stabilize the film morphology. Using the well-known low-cost P3HT:O-IDTBR as the model photoactive layer, OPVs with small weight amounts (less than 30%) of PY achieved comparable photovoltaic efficiencies. Notably, the 10%-ternary blend maintained over 70% of its initial efficiency after annealing at 150 degrees C for 8 days, while the efficiency of the binary system dropped rapidly. Notably, this approach was also effective for the high-efficiency PM6:BTP-eC9 blend. Combined with the morphology and crystallization characterization techniques, the relationship between microstructure and thermal stability was constructed. This work thus demonstrated an effective and broadly applicable strategy to improve the thermal stability of OPVs without sacrificing the initial efficiency.

Keyword:

crystallinity efficiency nonfullerene thermal stability third component

Community:

  • [ 1 ] [Qi, Qingchun]Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Sch Mat Sci & Engn, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300350, Peoples R China
  • [ 2 ] [Xian, Kaihu]Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Sch Mat Sci & Engn, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300350, Peoples R China
  • [ 3 ] [Ke, Huizhen]Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Sch Mat Sci & Engn, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300350, Peoples R China
  • [ 4 ] [Wu, Junjiang]Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Sch Mat Sci & Engn, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300350, Peoples R China
  • [ 5 ] [Zhou, Kangkang]Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Sch Mat Sci & Engn, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300350, Peoples R China
  • [ 6 ] [Gao, Mengyuan]Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Sch Mat Sci & Engn, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300350, Peoples R China
  • [ 7 ] [Liu, Junwei]Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Sch Mat Sci & Engn, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300350, Peoples R China
  • [ 8 ] [Li, Saimeng]Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Sch Mat Sci & Engn, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300350, Peoples R China
  • [ 9 ] [Ye, Long]Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Sch Mat Sci & Engn, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300350, Peoples R China
  • [ 10 ] [Ke, Huizhen]Minjiang Univ, Fujian Key Lab Novel Funct Text Fibers & Mat, Fuzhou 350108, Peoples R China
  • [ 11 ] [Ke, Huizhen]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350108, Peoples R China
  • [ 12 ] [Zhao, Wenchao]Nanjing Forestry Univ, Coll Mat Sci & Engn, Coinnovat Ctr Efficient Proc & Utilizat Forest Res, Nanjing 210037, Peoples R China
  • [ 13 ] [Chen, Zheng]Jilin Univ, Coll Chem, Key Lab High Performance Plast, Natl & Local Joint Engn Lab Synth Technol High Per, Changchun 130012, Peoples R China

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Source :

ACS APPLIED ENERGY MATERIALS

ISSN: 2574-0962

Year: 2022

Issue: 12

Volume: 5

Page: 15656-15665

6 . 4

JCR@2022

5 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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