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author:

Chen, Lu (Chen, Lu.) [1] | Chen, Feng (Chen, Feng.) [2] | Ying, Shaoming (Ying, Shaoming.) [3] | Liang, Ruowen (Liang, Ruowen.) [4] | Yan, Guiyang (Yan, Guiyang.) [5] | Wang, Xuxu (Wang, Xuxu.) [6] (Scholars:王绪绪) | Xia, Yuzhou (Xia, Yuzhou.) [7]

Indexed by:

EI SCIE

Abstract:

The rapid recombination of photogenerated carriers and strong photocorrosion have considerably limited the practical application of CdS in the field of photocatalysis. Loading a cocatalyst has been widely utilized to largely enhance photocatalytic activity. In the present work, a WC@C cocatalyst was prepared by a novel molten salt method and explored as an efficient noble-metal-free cocatalyst to significantly enhance the photocatalytic hydrogen evolution rate of CdS nanorods. The WC@C/CdS composite photocatalyst with a 7 wt% content of WC@C showed the highest photocatalytic hydrogen evolution rate of 8.84 mmol g(-1) h(-1), which was about 21 and 31 times higher than those of CdS and 7 wt% Pt/CdS under visible light irradiation. A high apparent quantum efficiency (AQY) of 55.28% could be achieved under 420 nm monochromatic light. Furthermore, the photocatalytic activity of the 7 wt% WC@C/CdS photocatalyst exhibited good stability for 12 consecutive cycles of the photocatalytic experiment with a total reaction time of 42 h. The excellent photocatalytic performance of the photocatalyst was attributed to the formation of a Schottky junction and the loading cocatalyst, which not only accelerated the separation of the photogenerated carrier but also provided a reactive site for hydrogen evolution. This work revealed that WC@C could act as an excellent cocatalyst for enhancing the photocatalytic activity of CdS nanorods.

Keyword:

Community:

  • [ 1 ] [Chen, Lu]Ningde Normal Univ, Fujian Prov Univ Key Lab Green Energy & Environm C, Dept Chem, Ningde 352100, Peoples R China
  • [ 2 ] [Chen, Feng]Ningde Normal Univ, Fujian Prov Univ Key Lab Green Energy & Environm C, Dept Chem, Ningde 352100, Peoples R China
  • [ 3 ] [Ying, Shaoming]Ningde Normal Univ, Fujian Prov Univ Key Lab Green Energy & Environm C, Dept Chem, Ningde 352100, Peoples R China
  • [ 4 ] [Liang, Ruowen]Ningde Normal Univ, Fujian Prov Univ Key Lab Green Energy & Environm C, Dept Chem, Ningde 352100, Peoples R China
  • [ 5 ] [Yan, Guiyang]Ningde Normal Univ, Fujian Prov Univ Key Lab Green Energy & Environm C, Dept Chem, Ningde 352100, Peoples R China
  • [ 6 ] [Xia, Yuzhou]Ningde Normal Univ, Fujian Prov Univ Key Lab Green Energy & Environm C, Dept Chem, Ningde 352100, Peoples R China
  • [ 7 ] [Wang, Xuxu]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [Chen, Lu]Ningde Normal Univ, Fujian Prov Univ Key Lab Green Energy & Environm C, Dept Chem, Ningde 352100, Peoples R China;;

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Source :

DALTON TRANSACTIONS

ISSN: 1477-9226

Year: 2022

Issue: 2

Volume: 52

Page: 290-296

4 . 0

JCR@2022

3 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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