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author:

Yin, Wang (Yin, Wang.) [1] (Scholars:尹旺) | Wang, Zhiwen (Wang, Zhiwen.) [2] | Yang, Huaizhou (Yang, Huaizhou.) [3] | Venderbosch, Robbie H. (Venderbosch, Robbie H..) [4] | Heeres, Hero Jan (Heeres, Hero Jan.) [5]

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EI Scopus SCIE

Abstract:

Biomass-derived fast pyrolysis liquids (PLs) are not directly applicable as transportation fuels due to their high oxygen content and limited storage stability. Catalytic hydrotreatment is an efficient technology to convert such PLs to finished fuels or intermediates that can be used as a co-feed for existing oil refinery units. In this paper, we report catalyst screening studies for the mild hydrotreatment of PLs using commercially available Ni and Cu-based PRICAT catalysts at rather mild conditions (200 degrees C, initial 140 bar H2 pressure) in a batch setup for 4 h. Among all catalysts, PRICAT NI 62/15 showed the best performance for mild catalytic hydrotreatment in terms of product properties (highest H/C ratio and lowest TG residue). The best catalysts were also tested for deep hydrotreatment at more severe conditions (350 degrees C, initial 100 bar H2 pressure). Here, the PRICAT NI catalysts showed better performance than the benchmark Picula Ni-Mo catalyst when considering oil yield and H/C ratio. Advantageously, the hydrogen consumption during deep hydrotreatment is also reduced, rationalized by a lower methanation activity.

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  • [ 1 ] [Yin, Wang]Fuzhou Univ, Fujian Univ Engn Res Ctr React Distillat Technol, Coll Chem Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Yin, Wang]Univ Groningen, Engn & Technol Inst Groningen ENTEG, Dept Chem Engn, , AG, NL-9747 Groningen, Netherlands
  • [ 3 ] [Wang, Zhiwen]Univ Groningen, Engn & Technol Inst Groningen ENTEG, Dept Chem Engn, , AG, NL-9747 Groningen, Netherlands
  • [ 4 ] [Yang, Huaizhou]Univ Groningen, Engn & Technol Inst Groningen ENTEG, Dept Chem Engn, , AG, NL-9747 Groningen, Netherlands
  • [ 5 ] [Heeres, Hero Jan]Univ Groningen, Engn & Technol Inst Groningen ENTEG, Dept Chem Engn, , AG, NL-9747 Groningen, Netherlands
  • [ 6 ] [Venderbosch, Robbie H.]Biomass Technol Grp BV, NL-7545PN Enschede, Netherlands

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Source :

ENERGY & FUELS

ISSN: 0887-0624

Year: 2022

5 . 3

JCR@2022

5 . 2 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 7

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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