Synthesis, Structures and Optical Limiting of Catecholato-Based Aluminum Oxo Clusters - Details

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Abstract：

Present　herein　is　the　currently　largest　catecholato-based　aluminum　oxo　clusters.　By　adjusting　the　amount　of　auxiliary　3,　5-dimethylpyrazole　ligands,　the　synthesis　of　aluminum　oxo　clusters　(AlOCs)　(AlOC-86)　to　high　nuclearity　AlOCs　(AlOC-88)　were　successfully　achieved.　Such　synthetic　strategy　is　applicable　to　imidazole　ligands　and　new　compounds　(AlOC-87　and　AlOC-89)　were　obtained.　Single　crystal　analysis　shows　that　AlOC-86　and　AlOC-87　are　hexanuclear　clusters　made　up　of　two　edge-sharing　tetrahedral　clusters.　The　nuclearity　of　compounds　AlOC-88　and　AlOC-89　is　doubled　and　they　are　S-shape　dodecanuclear　AlOCs.　The　aggregation　of　such　clusters　is　attributed　to　the　labile　sites　on　the　two　ends　of　the　hexanuclear　clusters.　In　addition,　open　aperture　(OA)　Z-scan　measurements　results　indicate　that　these　compounds　exhibit　manifest　reverse　saturation　absorption　(RSA)　response.　©　2022　Wiley-VCH　GmbH.

Keyword：

Aluminum Catechol Chelating ligand Clusters Optical limiting

Community：

[ 1 ] [Liu, Z.-H.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 2 ] [Liu, Z.-H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fujian, Fuzhou, 350002, China
[ 3 ] [Chen, R.-Q.]College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 4 ] [Chen, R.-Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fujian, Fuzhou, 350002, China
[ 5 ] [Wang, S.-T.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fujian, Fuzhou, 350002, China
[ 6 ] [Liu, Y.-J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fujian, Fuzhou, 350002, China
[ 7 ] [Fang, W.-H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fujian, Fuzhou, 350002, China
[ 8 ] [Zhang, J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fujian, Fuzhou, 350002, China

Reprint 's Address：

[Fang, W.-H.]State Key Laboratory of Structural Chemistry, Fujian, China

Email：

fwh@fjirsm.ac.cn

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Related Keywords：

Synthesis, Structures and Optical Limiting of Catecholato-Based Aluminum Oxo Clusters
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Source ：

European Journal of Inorganic Chemistry

ISSN： 1434-1948

Year： 2022

Issue： 29

Volume： 2022

2 . 3

JCR@2022

2 . 2 0 0

JCR@2023

ESI HC Threshold：74

JCR Journal Grade：2

CAS Journal Grade：3

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WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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