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Abstract:
Controlling the laser power density is one of the major means to bring photothermal conversion phenomenon. However, only a slight temperature enhancement was achieved by exposure to the laser. How to enhance photothermal conversion to develop power-sensitive fluorescence intensity ratio technology becomes a problem. Here, we report an eco-friendly niobate-based ceramic (K0.25Na0.25NbO3) doped with rare earth ions (Er3+, Yb3+) and simultaneously modified with CaCu3TiO4, exhibiting superior photothermal effect (PTE) and fluorescence intensity ratio (FIR). Thereinto, PTE originating from the up-conversion luminescence of Er3+ greatly elevates due to the Cu2+ quenching and Yb3+ sensitization. Meanwhile, the defects formed by the volatilization of potassium and sodium at high temperature can enhance PTE (70 °C, 0.4 W) and power sensitivity (Sp = 0.61 W-1). Under multiple power cycles, stable FIR of the ceramic shows outstanding resistance to temperature in long-term power-dependent tests. Furthermore, this strategy can open opportunities for preparing efficient photothermal conversion ceramics and exploiting PTE for vision-to-tactile sensory conversion. © 2022 Elsevier Ltd and Techna Group S.r.l.
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Ceramics International
ISSN: 0272-8842
Year: 2022
Issue: 17
Volume: 48
Page: 25431-25438
5 . 2
JCR@2022
5 . 1 0 0
JCR@2023
ESI HC Threshold:91
JCR Journal Grade:1
CAS Journal Grade:1
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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