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Improving the stability and charge transportation efficiency of lead halide perovskites is the key for their practical photocatalytic applications. Herein, we designed and synthesized a microporous boron imidazolate framework (BIF-122-Co) by cross-linking boron imidazolate ligands and benzene carboxylate with metal ions, which was further used as a host matrix to encapsulate CsPbBr3 perovskite via a sequential deposition route to obtain a composite material, CsPbBr3/BIF-122-Co. Due to the intimate host-guest interfacial contact in the composite material, BIF-122-Co not only provided a physical protective barrier for CsPbBr3 but also accelerated the photoinduced charge separation process in the photocatalytic CO2 reduction reaction. The work provided a guide for exploration of excellent perovskite/ metal-organic framework (MOF) composites.
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ACS APPLIED ENERGY MATERIALS
ISSN: 2574-0962
Year: 2021
Issue: 1
Volume: 5
Page: 1175-1182
6 . 9 5 9
JCR@2021
5 . 5 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:142
JCR Journal Grade:1
CAS Journal Grade:3
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