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[期刊论文]

Composite of CsPbBr3 with Boron Imidazolate Frameworks as an Efficient Visible-Light Photocatalyst for CO2 Reduction

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author:

Chen, Zhen-Yu (Chen, Zhen-Yu.) [1] | Hong, Qin-Long (Hong, Qin-Long.) [2] | Zhang, Hai-Xia (Zhang, Hai-Xia.) [3] | Unfold

Indexed by:

EI SCIE

Abstract:

Improving the stability and charge transportation efficiency of lead halide perovskites is the key for their practical photocatalytic applications. Herein, we designed and synthesized a microporous boron imidazolate framework (BIF-122-Co) by cross-linking boron imidazolate ligands and benzene carboxylate with metal ions, which was further used as a host matrix to encapsulate CsPbBr3 perovskite via a sequential deposition route to obtain a composite material, CsPbBr3/BIF-122-Co. Due to the intimate host-guest interfacial contact in the composite material, BIF-122-Co not only provided a physical protective barrier for CsPbBr3 but also accelerated the photoinduced charge separation process in the photocatalytic CO2 reduction reaction. The work provided a guide for exploration of excellent perovskite/ metal-organic framework (MOF) composites.

Keyword:

charge transfer CO2 reduction crystal structure perovskite photocatalysis

Community:

  • [ 1 ] [Chen, Zhen-Yu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Hong, Qin-Long]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Zhang, Hai-Xia]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Zhang, Jian]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Chen, Zhen-Yu]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

ACS APPLIED ENERGY MATERIALS

ISSN: 2574-0962

Year: 2021

Issue: 1

Volume: 5

Page: 1175-1182

6 . 9 5 9

JCR@2021

5 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:142

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 19

SCOPUS Cited Count: 19

30 Days PV: 2

查看更多>>操作日志

管理员  2025-02-20 21:59:01  更新被引

管理员  2025-02-20 21:59:00  更新被引

管理员  2024-08-27 05:24:58  更新被引

管理员  2024-07-29 13:14:57  更新被引

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