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author:

Luo, Chengsheng (Luo, Chengsheng.) [1] | Su, Longshui (Su, Longshui.) [2] | Wang, Chen (Wang, Chen.) [3] | Tong, Changqing (Tong, Changqing.) [4] | Zhou, Jianhui (Zhou, Jianhui.) [5] | Wang, Bingshu (Wang, Bingshu.) [6] | Chen, Junfeng (Chen, Junfeng.) [7]

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Abstract:

The corrosion behaviors of Cu–7.42Sn–0.156P and Cu–5.78Sn–0.162P alloys in different solutions were investigated. The results show that the Cu–Sn–P alloy with higher Sn content exhibits better corrosion resistance. In the NaCl, NaHCO3, and NaCl+NaHCO3 solutions, compared with Cu–5.78Sn–0.162P alloy, the corrosion current densities of Cu–7.42Sn–0.156P alloy are reduced by 25.2%, 36.9%, and 34.5%, and the polarization resistances are increased by 32.0%, 25.4%, and 29.9%. The Cu–Sn–P alloys have the best corrosion resistance in the NaHCO3 solution, followed by the NaCl solution and the worst in the NaCl + NaHCO3 solution. The increase of Sn is helpful to improve the density and spalling resistance of the corrosion film. There is a double-layer structure for the corrosion film of Cu–Sn–P alloy. For the alloys immersed in the NaCl solution and the NaCl+NaHCO3 solutions, the corrosion films consisted of Cu2O, CuO, and SnO2. For the alloys immersed in the NaHCO3 solution, the corrosion films are composed of Cu2O, CuO, SnO, and SnO2. The increase of Sn content in the alloy can increase the contents of Cu2O and SnO in the corrosion films. © 2022 Wiley-VCH GmbH.

Keyword:

Copper corrosion Copper oxides Corrosion resistance Corrosion resistant alloys Corrosive effects Electrochemical corrosion Sodium alloys Sodium bicarbonate Sodium chloride

Community:

  • [ 1 ] [Luo, Chengsheng]College of Materials Science and Engineering, Fuzhou University, Fujian, China
  • [ 2 ] [Su, Longshui]College of Materials Science and Engineering, Fuzhou University, Fujian, China
  • [ 3 ] [Wang, Chen]College of Materials Science and Engineering, Fuzhou University, Fujian, China
  • [ 4 ] [Tong, Changqing]School of Chemistry and Materials, Longyan University, Fujian, China
  • [ 5 ] [Zhou, Jianhui]Fujian Zijin Copper Co., Ltd., Fujian, China
  • [ 6 ] [Wang, Bingshu]College of Materials Science and Engineering, Fuzhou University, Fujian, China
  • [ 7 ] [Chen, Junfeng]College of Materials Science and Engineering, Fuzhou University, Fujian, China

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Source :

Materials and Corrosion

ISSN: 0947-5117

Year: 2022

Issue: 7

Volume: 73

Page: 1110-1120

1 . 8

JCR@2022

1 . 6 0 0

JCR@2023

ESI HC Threshold:91

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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